The spectroscopicstudies have been carried out for Indian Portland cement hydrated with distilled and sea water in a water to cement ratio of 0.4. This study aims to analyze the effect of water on Portland cement. FTIR, DTA, XRD and EPR studies were used to characterize the hydration reaction of the cement pastes. Experimental results on setting time, compressive strength are also reported. The unreacted clinker phases and g-factors are calculated. The results indicate that sea water accelerates the cement hydration at early stage but retards in the latter stage of hydration.

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The present work reports the effect of waste glass (WG) on the properties of Portland cement through Electron Paramagnetic Resonance (EPR) study. Cement pastes containing 0, 10, and 30% replacement of waste glass with cement and in a water to cement ratio of 0.4 have been prepared. The g factors of Fe(III) and Mn(II) impurities at different hydration ages have been calculated. The decreased g Fe values and simultaneous increase in g Mn values with increase in replacement % of WG are explained due to retardation of cement hydration.

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The present works reports the effect of Flyash on the properties of Portland cement hydrated with ground water and seawater through magnetic susceptibility study. Cement pastes containing 0, 10, 20, 30% replacement of flyash with cement and in a Water cement ratio (W/C) ratio of 0.4 have been prepared. The magnetic susceptibility at different hydration ages has been determined by Faraday Curie balance method and this has been correlated to changes in setting time and compressive strength measurement. The observed result shows that, irrespective of water the magnetic susceptibility increases with increasing flyash percentage replacement level in cement.

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