SO9 5NH)Summary Octadienyl and butenyl substituted amines reported. Tertiary phosphine complexes of palladium(0) have been shown to catalyse the reaction of buta-1,3-diene with methanol and phenol to give l-methoxyocta-2,7-diene and l-phenoxyocta-2,7-diene, respective1y.l Similar reactions have been demonstrated with primary and secondary A NUMBER of palladium complex-catalysed reactions of amines, carboxylic acids,2 9 3 and active-methylene and active-hydrogen compounds with buta-1,3-diene have been -methine compounds.4 have been prepared by reaction of primary and secondary amines with butadiene catalysed by nickel( 0) complexes.
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