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This paper deals with the development of a new process for the deposition of thermal barrier coatings (TBC) based on chemical vapor deposition (CVD). The research program started in September 1998 under a BRITE/Euram III project. The CVD process involves the evaporation of zirconium and yttrium starting from metal-organic precursors and their reaction with oxygen in a hot wall reactor in order to deposit TBC layers. The influence of different deposition parameters such as evaporation temperature, pressure, and substrate temperature on structure, deposition rate, and process yield are described. The characterization of different precursors behavior is also described. Preliminary results, obtained with optimized conditions, have shown ZrO2-Y2O3 columnar layers with deposition rates of interest from an industrial point of view.

Three experiments examine transfer from appetitive Pavlovian conditioning to appetitive instrumental responding by varying the similarity between conditions of Pavlovian reinforcement and instrumental reward. After conditioning with rats confined in a restraining device, a CS for electrical stimulation of the brain (ESB)produced substantial facilitation of operant responding for ESB, while a CS for food facilitated operant responding for food. However, no effects on rate of responding for food were seen during a CS for ESB. In a fourth experiment, four groups of rats were trained to barpress for rewarding electrical stimulation of the brain (ESB)and then given discriminative Pavlovian conditioning with ESB. The groups differed in the degree of similarity between the stimulus-response sequences present during Pavlovian conditioning and those occurring in instrumental responding. As similarity increased, so did the degree of conditioned facilitation in subsequent transfer tests. These results indicate that conditioned incentive responses or reinforcer-derived expectancies are specific to the conditions under which they develop,rather than generalized emotional or motivational responses.

The identification of those skill sets required for deployment is in keeping with the General Medical Council's current drive towards credentialing consultants, by which a consultant surgeon's capabilities in particular practice areas would be defined. Limited opportunities currently exist for trainees and consultants to gain experience in the management of traumatic head, face, neck and eye injuries seen in a kinetic combat environment. Predeployment training requires that the surgical techniques described in this paper are covered and should form the curriculum of future military-specific surgical fellowships. Relevant continued professional development will be necessary to maintain required clinical competency.

Moisture content (MC) of green biomass or raw biomass materials (wood, bark, plants, etc.) commonly exceeds 50 mass % (wet basis). The maximum possible MC of biomass fuel for big scale combustion (e.g. fluidized bed combustion with low external heat losses) is approximately 60–65 mass %. Higher biomass MC generally causes operational problems of biomass combustors, lower stability of burning and higher CO and VOC emissions. Gasification of biomass with higher MC produces fuel gas of lower effective heating values and higher tar concentrations. In this review, various technological schemes for wood drying in combination with combustion/gasification with the assessment of factors for possible minimization of emissions of organics from the drying processes are compared. The simple direct flue gas biomass drying technologies lead to exhaust drying gases containing high VOC emissions (terpenes, alcohols, organic acids, etc.). VOC emissions depend on the drying temperature, residence time and final MC of the dried biomass. Indirect biomass drying has an advantage in the possibility of reaching very low emissions of organic compounds from the drying process. Exhaust drying gases can be simply destroyed as a part of the total combustion air (gas) in a combustion chamber or a gasifier. Liquid, condensed effluents have to be treated properly because they have relatively high content of organic compounds, some of them accompanied by odor. Drying of biomass with superheated steam offers more uniform drying of both small and bigger particles and shorter periods of higher temperatures of the dried biomass, particularly if drying to the final MC below 15 mass % is required. In practical modern drying technologies, biomass (mainly wood) is dried in recirculated gas of relatively high humidity (approaching saturation) and the period of constant rate drying is longer. Drying of moist wood material (saw dust, chips, etc.) is required in wood pellet production. Emissions of organics in drying depend on biomass properties, content of resins, storing time and on operational aspects of the drying process: drying temperature, drying medium, final MC, residence time, and particle size distribution of the dried biomass (wood). Integration of biomass drying with combustion/gasification processes includes the choice of the drying medium (flue gas, air, superheated steam). Properties of the drying media and operational parameters are strongly dependent on local conditions, fuel input of the combustion/gasification unit, cleaning of the exhaust drying media (gas, steam, wastewater), and on environmental factors and requirements.