We propose a facile synthesis approach for nitrogen doped porous carbon and demonstrate a novel pore-forming method that iron nanoclusters act as a template or activator at different carbonization temperatures based on Fe-poly(4-vinyipyridine) (P4VP) coordination. P4VP will completely decompose even in an inert atmosphere, but under the coordination and catalysis of Fe, it can be converted to carbon at a very low temperature (400 °C). The aggregation of iron nanoclusters in the carbonization process showed different pore-forming methods at different temperatures. The as-prepared materials possess high specific surface area (up to 1211 m g), large pore volume (up to 0.96 cm g), narrow microporosity, and high N content (up to 9.9 wt %). Due to these unique features, the materials show high CO uptake capacity and excellent selectivity for CO/N separation. The CO uptake capacity of NDPC-2-600 is up to 6.8 and 4.3 mmol g at 0 and 25 °C; the CO/N (0.15/0.85) selectivity at 0 and 25 °C also reaches 18.4 and 15.2, respectively.
The detection of some environmental pollutants remains still a great challenge and the current methods suffer from low sensitivity, reproducibility and require sophisticated instruments. Here, a simple, sensitive and pH‐responsive electrochemical sensor for the detection of hydroquinone (HQ) was developed based on a pH‐responsive block copolymer polystyrene‐b‐poly(acrylic acid) (PS‐b‐PAA) and graphene oxide (GO) composite film (PG) modified glassy carbon electrode (GCE). The electrochemical behaviors of HQ at the modified GCE (PG/GCE) electrode were studied by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The peak current of the PG/GCE electrode toward HQ was significantly enhanced at pH 7.0 and greatly suppressed below pH 6.0, which are caused by swelling and shrinking of pH‐responsive block copolymer and the synergistic effect with GO. The PG/GCE exhibited a reversible “On/Off” switch for the HQ electrochemical behaviors between pH 4.0 and pH 7.0. When the pH of the medium is 7.0, the PG complex film on the PG/GCE is in the “On” state, the linear detection range of HQ is from 16 μM to 104 μM with a detection limit as low as 0.34 μM. Furthermore, the PG/GCE can also successfully detect the HQ concentration of the lake water sample with satisfactory recovery, indicating that the pH‐responsive block copolymer/GO‐functionalized sensor provided a powerful avenue for simple, sensitive and convenient detection of HQ, which can be translated into practical application.
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