National inventories of anthropogenic greenhouse gas (GHG) emissions (implementation of the National Communications) are organized according to five main sectors, namely: Energy, Industrial Processes, Agriculture, Land-Use Change and Forestry (LUCF) and Waste. The objective of this study was to review and calculate the potential of greenhouse gas mitigation strategies in Brazil for the Agricultural and LUCF. The first step consisted in an analysis of Brazilian official and unofficial documents related to climate change and mitigation policies. Secondly, business as usual (BAU) and mitigation scenarios were elaborated for the 2010-2020 timeframe, and calculations of the corresponding associated GHG emissions and removals were performed. Additionally, two complementary approaches were used to point out and quantify the main mitigation options: a) following the IPCC 1996 guidelines and b) based on EX-ACT. Brazilian authorities announced that the country will target a reduction in its GHG between 36.1 and 38.9% from projected 2020 levels. This is a positive stand that should also be adopted by other developing countries. To reach this government goal, agriculture and livestock sectors must contribute with an emission reduction of 133 to 166 Mt CO 2 -eq. This seems to be reachable when confronted to our mitigation option values, which are in between the range of 178.3 to 445 Mt CO 2 -eq. Government investments on agriculture are necessary to minimize the efforts from the sectors to reach their targets. Key words: IPCC, EX-ACT, emission reduction, carbon fixation Opções de mitigação de gases do efeito estufa na mudança do uso da terra, pecuária e agricultura no Brasil RESUMO: Inventários nacionais acerca de emissões de gases do efeito estufa (GEE) (refinamentos das Comunicações Nacionais) são organizadas de acordo com cinco principais setores, a saber: Energia, Processos Industriais, Agropecuária, Mudanças do Uso da Terra e Florestas e Tratamento de Resíduos. O objetivo dessa revisão foi calcular o potencial das estratégias de mitigação de GEE no Brasil para agropecuária e mudança de uso da terra e florestas. A primeira etapa consistiu na análise de documentos oficiais e não-oficiais do Brasil relacionados a mudanças climáticas e políticas de mitigação. O cenário atual, sem adoção de ações mitigadoras (BAU), e os cenários de mitigação foram elaborados para o período 2010-2020. Efetuaram-se os cálculos associados às emissões e remoções de GEE. Adicionalmente, duas estratégias foram utilizadas para destacar e quantificar as principais opções de mitigação: a) seguindo metodologia do IPCC 1996 e b) baseando-se no EX-ACT. Autoridades brasileiras anunciaram que o país buscará reduzir sua taxa de emissão de GEE em 36.1 a 38.9% em relação a 2020. Este é um posicionamento positivo que deve ser adotado por outros países em desenvolvimento. Para alcançar essa meta governamental, os setores agricultura e pecuária devem contribuir reduzindo a emissão em 133 a 166 Mt CO 2 -eq. Tal redução parece ser atingível quando confr...

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The adsorption of heavy metals in soils affects their behavior in the environment and their bioavailability to plants. The knowledge of the adsorption mechanisms in competitive systems allows a more realistic evaluation of the metals' behavior in the soil than the single metal adsorption. The objectives of this study were (i) to evaluate Cd, Cu, Ni, and Zn adsorption in 14 surface samples (0-0.2 m) of representative soils of the Brazilian humid-tropical region, in competitive and non-competitive systems, and (ii) to establish metal affinity sequences for each soil, based in the maximum adsorption capacity (MAC) estimated by the Langmuir model. The Rhodic Eutrudox, the Kandiudalf Eutrudox, the Arenic Hapludalf, the Arenic Hapludult and the Typic Argiudoll had the highest metals' adsorption capacity, whereas the Typic Quartzipsamment and the sandy-textured Arenic Hapludult had the lowest values. In general, the MAC values for metals were lower in the competitive than in the non-competitive system. In the non-competitive system, the most common affinity sequence was Cu > Zn > Ni > Cd, whereas the most common sequence was Cu > Cd > Zn > Ni in the competitive system. In general, the Langmuir model fitted well the adsorption data of metals on the studied soils.

Soil bulk density values are needed to convert organic carbon content to mass of organic carbon per unit area. However, field sampling and measurement of soil bulk density are labour-intensive, costly and tedious. Near-infrared reflectance spectroscopy (NIRS) is a physically non-destructive, rapid, reproducible and low-cost method that characterizes materials according to their reflectance in the near-infrared spectral region. The aim of this paper was to investigate the ability of NIRS to predict soil bulk density and to compare its performance with published pedotransfer functions. The study was carried out on a dataset of 1184 soil samples originating from a reforestation area in the Brazilian Amazon basin, and conventional soil bulk density values were obtained with metallic "core cylinders". The results indicate that the modified partial least squares regression used on spectral data is an alternative method for soil bulk density predictions to the published pedotransfer functions tested in this study. The NIRS method presented the closest-to-zero accuracy error (−0.002 g cm −3 ) and the lowest prediction error (0.13 g cm −3 ) and the coefficient of variation of the validation sets ranged from 8.1 to 8.9% of the mean reference values. Nevertheless, further research is required to assess the limits and specificities of the NIRS method, but it may have advantages for soil bulk density predictions, especially in environments such as the Amazon forest.

O tipo de uso da terra anterior ao plantio de café e o manejo de podas adotado no cafezal podem condicionar a dinâmica do carbono (C) e do nitrogênio (N) no solo. Desta forma, o objetivo neste trabalho foi quantificar os estoques de C e N do solo nas três principais regiões produtoras de café de Minas Gerais, avaliando diferentes sistemas de manejo e cultivo do café em comparação com pastos cultivados. Para o cálculo dos estoques foram coletadas amostras de solo para determinação dos teores de C e N, além da densidade em diferentes profundidades. As avaliações incluem manejo das áreas com e sem podas, e o tipo de uso da terra anterior ao cultivo do café. Os resultados indicam que o cultivo do café sobre áreas de pastagem, com adoção de boas práticas agrícolas como um manejo adequado de podas e bom controle do mato, propicia a manutenção dos estoques de carbono e nitrogênio do solo. Através deste fato pode-se mencionar que a cafeicultura reflete positivamente na saúde do solo.

Background, aim, and scope The retention of potentially toxic metals in highly weathered soils can follow different pathways that variably affect their mobility and availability in the soil-water-plant system. This study aimed to evaluate the effects of pH, nature of electrolyte, and ionic strength of the solution on nickel (Ni) adsorption by two acric Oxisols and a less weathered Alfisol. Materials and methods The effect of pH on Ni adsorption was evaluated in surface and subsurface samples from a clayey textured Anionic 'Rhodic' Acrudox (RA), a sandyclayey textured Anionic 'Xantic' Acrudox (XA), and a heavy clayey textured Rhodic Kandiudalf (RK). All soil samples were equilibrated with the same concentration of Ni solution (5.0 mg L −1 ) and two electrolyte solutions (CaCl 2 or NaCl) with different ionic strengths (IS) (1.0, 0.1 and 0.01 mol L −1 ). The pH of each sample set varied from 3 to 10 in order to obtain sorption envelopes. Results and discussion Ni adsorption increased as the pH increased, reaching its maximum of nearly pH 6. The adsorption was highest in Alfisol, followed by RA and XA. Competition between Ni 2+ and Ca 2+ was higher than that between Ni 2+ and Na + in all soil samples, as shown by the higher percentage of Ni adsorption at pH 5. At pH values below the intersection point of the three ionic strength curves (zero point of salt effect), Ni adsorption was generally higher in the more concentrated solution (highest IS), probably due to the neutralization of positive charges of soil colloids by Cl − ions and consequent adsorption of Ni 2+ . Above this point, Ni adsorption was higher in the more diluted solution (lowest ionic strength), due to the higher negative potential at the colloid surfaces and the lower ionic competition for exchange sites in soil colloids. Conclusions The effect of ionic strength was lower in the Oxisols than in the Alfisol. The main mechanism that controlled Ni adsorption in the soils was the ionic exchange, since the adsorption of ionic species varied according to the variation of pH values. The ionic competition revealed the importance of electrolyte composition and ionic strength on Ni adsorption in soils from the humid tropics. Recommendations and perspectives The presence of NaCl or CaCl 2 in different ionic strengths affects the availability of heavy metals in contaminated soils. Therefore, the study J Soils Sediments (2008) 8:442-451