[1] Seismic data and seafloor samples indicate the presence of free gas, gas hydrate, and fluid seeps south of the Gorda Escarpment, a topographic feature that marks the eastern end of the Gorda/Pacific transform plate boundary southwest of Cape Mendocino, California. In spite of high sedimentation rates and high biological productivity, direct or indirect indicators of gas hydrate presence had not previously been recognized in this region, or along transform margins in general. Gas is indicated by a bottom simulating reflection (BSR) observed near the Gorda Escarpment, by ''bright spots'' and ''gas curtains'' scattered throughout the sedimentary basin to the south, and by d
C and d18 O isotopes of carbonates, which are similar to those recovered from other hydrate-bearing regions. The BSR reflection coefficient of À0.13 ± 0.04 and interval velocities as low as 1.38 km/s indicate that free gas is present beneath the BSR. Local shallowing of the BSR toward the north facing Gorda Escarpment and beneath a channel near the crest suggests fluid flow toward the seafloor. Integrating these various observations, we suggest a scenario in which methane is formed in thick Miocene and Pliocene deposits of organicrich sediments that fill the marginal basin south of the transform fault. Dissolved and free gas migrates toward the escarpment along stratigraphic horizons, resulting in hydrate formation and in channels, slumps and chemosynthetic communities on the face of the escarpment. We conclude that the BSR appears where hydrate-bearing sediments are uplifted because of current triple junction tectonics.
In order to elucidate how mineralogy and composition of crustal sources influences production of leucogranite magmas, we modelled the potential fertility of a sequence of metapelites and metagraywackes from the Black Hills, South Dakota, U.S.A., using a least-squares mixing approach. Rocks analogous to the Black Hills schists were the sources of the Harney Peak leucogranite. Both muscovite and biotite fluid-absent melting reactions (MM and BM, respectively) were investigated. Using the Harney Peak Granite composition as the melt analogue and mineral compositions from the schists for mixing calculations, it is shown that MM of metapelites would lead to highly variable residue mineralogy in the investigated samples. The average residue includes 36 wt.% biotite, 32 wt.% quartz, 12 wt.% plagioclase, 8 wt.% K-feldspar, 9 wt.% sillimanite and 2 wt.% garnet. Melt production ranges from 5% to 23% with an average of 14%. It is limited by the amount of H2O that must be in the melt at the conditions of melting, relative to the amount that is in muscovite in the source rocks. Plagioclase-rich metagraywackes contain little to no muscovite, thus MM cannot occur in them.Although BM is continuous over a wide temperature range, for the purposes of modelling melting at 975°C and 10kbar was chosen. The temperature is near the terminal stability of biotite, thus the calculations give near-maximum melt production. At this temperature, the mineralogy of the model residues from both metapelites and metagraywackes is dominated by garnet. The potential melt production in the metapelites ranges from 0% to 58% with an average of 32%. It is limited by the availability of plagioclase in the source rocks. Potential melt production in the metagraywackes ranges from 9% to 37% with an average of 23%. At the chosen conditions of melting, melt production is limited by the available K in biotite, although at lower temperatures, the available H2O limits melt production. The total potential melt production (MM + BM) in the metapelites is higher because they have on average a low normative An/Ab ratio (0·14) that approaches the ratio in the leucogranites (0·04). The paragonite component in muscovite significantly contributes to the low ratio in the metapelites. The higher ration (0·27) in the metagraywackes is denned by the feldspar composition.Using the calculated melt fractions and residue mineralogies, we modelled the concentrations of Rb, Sr and Ba in the melts, as these elements are important indicators of melt-generating processes. The results indicate that both Sr and Ba are likely to be heterogeneous in extracted melt batches and will be depleted in partial melts relative to their pelitic sources, irrespective of whether the melting is fluid-absent or fluid-present.
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