A series of new monomers of 2,5-bis[(4-tertbutyl-phenyl)-1,3,4-oxadiazole] styrene (M-Ct) and
2,5-bis[(4-alkoxy-phenyl)-1,3,4-oxadiazole]styrene (M−OCm, m is the number of the carbons in the alkoxy groups,
m = 8, 10, 12, 14) were synthesized. Conventional radical polymerization of the monomers resulted in a series
of new mesogen-jacketed liquid crystalline polymer (MJLCP) containing the 1,3,4-oxadiazole unit. The chemical
structures of the monomers were confirmed by elemental analysis, mass spectrometry, 1H NMR, and IR. The
molecular characterization of the corresponding polymers of P-Ct and P-OCms was performed with 1H NMR,
gel permeation chromatography, and thermogravimetric analysis. Their phase structures and transitions were
investigated by differential scanning calorimetry, wide-angle X-ray diffraction, and polarized light microscopy
experiments. The P-Ct formed the hexatic columnar nematic (ΦHN) phase that is typical for MJLCPs, wherein
the chain molecules were rodlike. The P-OCms exhibited a well-defined smectic A (SA) phase. As the mesogenic
group is laterally jacketed to the polyethylene backbone through a single carbon−carbon bond, the P-OCm molecule
in the SA phase should be more or less ribbonlike with the backbone squeezed by the parallel aligned side chains
on both sides. The transition of the four P-OCms follows the sequence of SA ↔ N ↔ I. The comparison between
P-Ct and P-OCms indicates that the flexibility of the side-chain tails is crucial to determine the LC structures.
Namely, simply changing the chemical structures of small portion of the MJLCP may greatly vary the molecular
packing behavior and thus the molecular shape in LC phase structures.
A series of waterborne polyurethanes (WPUs) with different contents of reactive organophosphonate were well prepared. Their structures were characterized by Fourier transform infrared and 1 H-NMR spectroscopy. Thermogravimetry and derivative thermogravimetry revealed that the WPU films containing phosphorus possessed lower onset and maximum degradation temperatures but higher char yields. Differential scanning calorimetry analysis suggested phase mixing of the hard and soft domains. The mechanical properties decreased with increasing amount of organophosphonate, whereas the limiting oxygen index results of the WPU films indicate that the flame retardancy was improved significantly by the incorporation of organophosphonate. The water uptake values of the organophosphonate-containing WPU films were higher than those of the phosphorusfree ones, whereas the static contact angles of the films indicated that the surface hydrophilic properties were not affected by segmenting in this phosphorus-containing oligomer.
Flame-retardant waterborne polyurethanes with a phosphorus-containing flame retardant diamine (AWPUs) were synthesized and characterized by the method of post-chain extension technology.
The swelling properties of different chitosan-poly(vinyl alcohol) (PVA) hydrogels were investigated as functions of the medium pH and salt concentration. The maximum swelling ability of the hydrogels was at a buffer pH of approximately 3, regardless of the PVA content in the hydrogels. The maximum mass of the swollen hydrogels was about 13 times that of their contracted counterparts. The cyclical swelling and contraction between pH 3 and pH 7 buffers and pH 3 and pH 3 buffers with salt confirmed the Donnan swelling mechanism of these hydrogels. The swelling mechanism was considered the transfer of water molecules driven by a concentration gradient. This was represented by a simplified mass-balance model, which neglected the effect of the ionization reaction, for the initial swelling period. The effective mass-transfer coefficient of water molecules during swelling, estimated with this model, gradually decreased with increasing PVA content in the hydrogels.
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