In terms of new-generation energy-storing devices, aqueous zinc-ion batteries (AZIBs) are becoming the prime candidates because of their inexpensive nature, inherent safety, environmental benignity and abundant resources. Nevertheless, due to a restrained selection of cathodes, AZIBs often perform unsatisfactorily under long-life cycling and high-rate conditions. Consequently, we propose a facile evaporation-induced self-assembly technique for preparing V2O3@carbonized dictyophora (V2O3@CD) composites, utilizing economical and easily available biomass dictyophora as carbon sources and NH4VO3 as metal sources. When assembled in AZIBs, the V2O3@CD exhibits a high initial discharge capacity of 281.9 mAh g−1 at 50 mA g−1. The discharge capacity is still up to 151.9 mAh g−1 after 1000 cycles at 1 A g−1, showing excellent long-cycle durability. The extraordinary high electrochemical effectiveness of V2O3@CD could be mainly attributed to the formation of porous carbonized dictyophora frame. The formed porous carbon skeleton can ensure efficient electron transport and prevent V2O3 from losing electrical contact due to volume changes caused by Zn2+ intercalation/deintercalation. The strategy of metal-oxide-filled carbonized biomass material may provide insights into developing high-performance AZIBs and other potential energy storage devices, with a wide application range.
Food packaging nowadays is not only essential to preserve food from being contaminated and damaged, but also to comply with science develop and technology advances. New functional packaging materials with degradable features will become a hot spot in the future. By far, plastic is the most common packaging material, but plastic waste has caused immeasurable damage to the environment. Cellulose known as a kind of material with large output, wide range sources, and biodegradable features has gotten more and more attention. Cellulose-based materials possess better degradability compared with traditional packaging materials. With such advantages above, cellulose was gradually introduced into packaging field. It is vital to make packaging materials achieve protection, storage, transportation, market, and other functions in the circulation process. In addition, it satisfied the practical value such as convenient sale and environmental protection, reduced cost and maximized sales profit. This review introduces the cellulose resource and its application in composite packaging materials, antibacterial active packaging materials, and intelligent packaging materials. Subsequently, sustainable packaging and its improvement for packaging applications were introduced. Finally, the future challenges and possible solution were provided for future development of cellulose-based composite packaging materials.
Multichannel-porous carbon derived from wood can serve as a conductive substrate for fast charge transfer and ion diffusion, supporting the high-theory capacitance of pseudocapacitive materials. Herein, NiCo2O4 nanosheets, which are hierarchically porous, anchored on the surface of carbonized wood via electrodeposition for free-binder high-performance supercapacitor electrode materials, were proposed. Benefiting from the effectively alleviated NiCo2O4 nanosheets accumulation and sufficient active surface area for redox reaction, a N-doped wood-derived porous carbon-NiCo2O4 nanosheet hybrid material (NCNS–NCW) electrode exhibited a specific electric capacity of 1730 F g−1 at 1 A g−1 in 1 mol L−1 KOH and splendid electrochemical firmness with 80% capacitance retention after cycles. Furthermore, an all-wood-based asymmetric supercapacitor based on NCNS–NCW//NCW was assembled and a high energy density of 56.1 Wh kg−1 at a watt density of 349 W kg−1 was achieved. Due to the great electrochemical performance of NCNS–NCW, we expect it to be used as an electrode material with great promise for energy storage equipment.
Phosphorene, also known as black phosphorus nanosheet (BPNS), has been investigated as a nanoagent for tumor therapy. However, promoting its intracellular accumulation while preventing the cytoplasmic decomposition remains challenging. Herein, for the first time, we propose a chiral BPNS designed through surface engineering based on amino acids with high biocompatibility and an abundant source for application in chirality-dependent tumor phototherapy based on its intracellular metabolism. The advantage of using cysteine (Cys) over other amino acids was that its d, l, or dl-form could efficiently work as the chirality inducer to modify the BPNS through electrostatic interaction and prevent alterations in the intrinsic properties of the BPNS. In particular, d-Cys-BPNS displayed an approximately threefold cytotoxic effect on tumor cells compared with l-Cys-BPNS, demonstrating a chirality-dependent therapy behavior. d-Cys-BPNS not only promoted high intracellular content but also showed resistance to cytoplasmic decomposition. Cys-engineered BPNS also demonstrated chirality-dependent phototherapy effects on tumor-bearing mice, in proximity to the results in vitro. Chiral engineering is expected to open new avenues that could promote the use of BPNS in tumor phototherapy and boost chiral nanomedicine.
As a kind of soft smart material, hydrogel actuators have extensive development prospects, but it is still difficult for these actuators to integrate multiresponsiveness, multiple remote actuation, high strength, fast responsiveness, and programmable complex deformation. Herein, we have explored an anisotropic bilayer hydrogel actuator with an Fe 3 O 4 /co-poly-(isopropylacrylamide-4-benzoylphenyl acrylate) [Fe 3 O 4 /P-(NIPAM-ABP)] active layer and an isotropic conductive adhesive (ICAs) passive layer based on the layer-by-layer method. Benefiting from the fibrosis and porosity of the Fe 3 O 4 / P(NIPAM-ABP) hydrogel, the ICAs-Fe 3 O 4 /P(NIPAM-ABP) hydrogel actuator has excellent mechanical strength (tensile strength of 3.1 ± 0.3 MPa) and response speed (temperature (45 °C): bending speed of 2400.3°/s; near-infrared (NIR) light: bending speed of 356.4°/s; electricity (2 V): bending speed of 180°/s; water (10 °C): recovery speed of 30.0°/s). In addition, the good photothermal properties and magnetic conductivity of Fe 3 O 4 nanoparticles provide precise remotely controllable light-and magnetic-actuated properties for the hydrogel actuator. The Ag microsheets with excellent conductivity (1.4 × 10 4 S/cm) provide remotely controllable electrical-actuated property for the hydrogel actuator. Combined with the responsiveness of P(NIPAM-ABP), the actuator can achieve short-range actuation including temperature-, ethanol-, and salt-responses. More importantly, it can achieve remote actuation including light, electrical, and magnetic responses. Finally, the Fe 3 O 4 /P(NIPAM-ABP) fibers can provide excellent anisotropic structures for the actuator to achieve precise deformational programmability. Inspired by some phenomena in nature, several actuating devices with the above characteristics have been successfully developed. This study can provide a general method for multifunctional anisotropic hydrogel actuators and will provide a new strategy for exploring smart materials suitable for complex bioinspired systems.
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