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The wild environment is unpredictable where soaring or plummeting temperatures in extreme weather events can pose serious threats to human lives. Incorporating passive evaporative cooling and controllable electric heating into clothing could effectively protect human beings from such harsh environments. In this work, poly(3,4-ethylene dioxy thiophene):poly(styrene sulfonate)/poly(ethylene glycol) (PPP) fibers with the core–shell structure and attractively textured surface have been successfully prepared via a single-nozzle wet-spinning technique. Results show that the fibers possess fascinating specific surface area (184.8 m2·g–1), electrical conductivity (50 S·cm–1), and stretchability (>100%) because of the novel preparation method and hierarchical morphological design. Through simple textile manufacturing routes, PPP fibers can be woven into fabrics easily, which exhibit desirable breathability, washability, and mechanical strength for smart textiles while maintaining favorable hygroscopicity. Benefiting from the textured structure with large specific surface area, PPP fabric exhibits attractile evaporative cooling rate. Practical application tests have demonstrated that under direct sunlight, the surface temperature of the PPP fabric is ∼5.2 and ∼10.8 °C lower than commercial cotton and polyester fabrics, respectively. Meanwhile, as conductive fibers, the resultant PPP fabric can heat under low-power electricity, therefore achieving the effect of “warmth in winter and coolness in summer”. The facile fabrication process and elevated performance of PPP fibers present significant advantages for applications in intelligent garments and textiles, as well as comprehensive personal thermal management, which opens a new avenue for future design in these fields.

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