This review provides an overview of the current state‐of‐the‐art of the emerging field of flexible multifunctional sensors for wearable and robotic applications. In these application sectors, there is a demand for high sensitivity, accuracy, reproducibility, mechanical flexibility, and low cost. The ability to empower robots and future electronic skin (e‐skin) with high resolution, high sensitivity, and rapid response sensing capabilities is of interest to a broad range of applications including wearable healthcare devices, biomedical prosthesis, and human–machine interacting robots such as service robots for the elderly and electronic skin to provide a range of diagnostic and monitoring capabilities. A range of sensory mechanisms is examined including piezoelectric, pyroelectric, piezoresistive, and there is particular emphasis on hybrid sensors that provide multifunctional sensing capability. As an alternative to the physical sensors described above, optical sensors have the potential to be used as a robot or e‐skin; this includes sensory color changes using photonic crystals, liquid crystals, and mechanochromic effects. Potential future areas of research are discussed and the challenge for these exciting materials is to enhance their integration into wearables and robotic applications.
This paper reports a self-powered, flexible, piezo-and pyro-electric hybrid nanogenerator (NG) device that can be fixed on different locations of human skin for detecting static and dynamic pressure variations and can also monitor temperature fluctuations during the respiration process. An efficient and cost-effective fabrication strategy has been developed to create electrospun poly(vinylidene fluoride) (PVDF)/ graphene oxide (GO) nanofibers, which are used to create a highly sensitive wearable pressure sensor and pyroelectric breathing sensor. The sensor can accurately and rapidly detect pressures as low as 10 Pa with a high sensitivity (4.3 V/kPa), a key performance indicator for wearable sensors. Importantly, the sensor exhibits a high sensitivity to bending and stretching by finger, wrist, and elbow. The pressure sensor is also highly sensitive to vocal vibrations when attached to the human throat. The device can generate a maximum output power density of ∼6.2 mW/m 2 when subjected to a compressive stress, which enhances its range of applications. Moreover, it is demonstrated that doping with GO improves the pyroelectric energy harvesting and sensing performance of the device under repeated temperature fluctuations. The PVDF/GO-based nanogenerator has a maximum pyroelectric output power density of ∼1.2 nW/m 2 and can sense temperature changes during respiration, which makes it promising as a pyroelectric breathing sensor. It is demonstrated that processing of the PVDF-GO self-powered multifunctional pressure and pyroelectric breathing sensor can be up-scaled for fabricating compact and high-performance electronic skins for application in health monitoring, motion detection, and portable electronics.
Dielectric elastomers are of interest for actuator applications due to their large actuation strain, high bandwidth, high energy density, and their flexible nature. If future dielectric elastomers are to be used reliably in applications that include soft robotics, medical devices, artificial muscles and electronic skins, there is a need to design devices that are tolerant to electrical and mechanical damage. In this paper, we provide the first report of self-healing of both electrical breakdown and mechanical damage in dielectric actuators using a thermoplastic methyl thioglycolate modified styrene-butadiene-styrene (MGSBS) elastomer. The self-healing functions are examined from the material to device level by detailed examination of the healing process, and characterisation of electrical properties and actuator response before and after Complete Manuscript
Energy harvesting is a topic of intense interest that aims to convert ambient forms of energy such as mechanical motion, light and heat, which are otherwise wasted, into useful energy. In many cases the energy harvester or nanogenerator converts motion, heat or light into electrical energy, which is subsequently rectified and stored within capacitors for applications such as wireless and self-powered sensors or low-power electronics. This review covers the new and emerging area that aims to directly couple energy harvesting materials and devices with electro-chemical systems. The harvesting approaches to be covered include pyroelectric, piezoelectric, triboelectric, flexoelectric, thermoelectric and photovoltaic effects. These are used to influence a variety of electro-chemical systems such as applications related to water splitting, catalysis, corrosion protection, degradation of pollutants, disinfection of bacteria and material synthesis. Comparisons are made between the range harvesting approaches and the modes of operation are described. Future directions for the development of electro-chemical harvesting systems are highlighted and the potential for new applications and hybrid approaches are discussed.
Energy harvesting is an important developing technology for a new generation of self-powered sensor networks. This paper demonstrates the significant improvement in the piezoelectric energy harvesting performance of barium titanate by forming highly aligned porosity using freeze casting. Firstly, a finite element model demonstrating the effect of pore morphology and angle with respect to poling field on the poling behaviour of porous ferroelectrics was developed. A second model was then developed to understand the influence of microstructure-property relationships on the poling behaviour of porous freeze cast ferroelectric materials and their resultant piezoelectric and energy harvesting properties. To compare with model predictions, porous barium titanate was fabricated using freeze casting to form highly aligned microstructures with excellent longitudinal piezoelectric strain coefficients, d33. The freeze cast barium titanate with 45 vol.% porosity had a d33 = 134.5 pC/N, which compared favourably to d33= 144.5 pC/N for dense barium titanate. The d33 coefficients of the freeze cast materials were also higher than materials with uniformly distributed spherical porosity due to improved poling of the aligned microstructures, as predicted by the models. Both model and experimental data indicated that introducing porosity provides a large reduction in the permittivity (𝜀 "" # ) of barium titanate, which leads to a substantial increase in energy harvesting figure of merit, 𝑑 "" % /𝜀 "" # , with a maximum of 3.79 pm 2 /N for barium titanate with 45 vol.% porosity, compared to only 1.40 pm 2 /N for dense barium titanate. Dense and porous barium titanate materials were then used to harvest energy from a mechanical excitation by rectification and storage of the piezoelectric charge on a capacitor. The porous barium titanate charged the capacitor to a voltage of 234 mV compared to 96 mV for the dense material, indicating a 2.4-fold increase that was similar to that predicted by the energy harvesting figures of merit.
Broader contextSelf-powered electronic devices that utilize energy harvesting technology for scavenging ambient energy are highly desirable for next generation wireless and wearable devices since it enables them to work without an external power source and eliminates the need for replacement and management of batteries. Flexible piezoelectric and piezo-composite materials have been directly used as self-powered sensors, but their poor piezoelectric properties and difficulty in achieving various sensing modes, such as the shear sensing mode, limit their performance and applications. In this work, we develop a flexible and highly active piezoelectric polymer composite material using a freeze casting method. The connected piezoelectric phase in the polymer matrix and the combined effect of compression and flexure allow the composites to achieve a high effective piezoelectric coefficient. The unique structure of the ceramic-polymer composite also allows the self-powered sensor to maintain high activity after bending to a small radius. The freeze casting method allows the production of complex device architectures. Using such piezo-composites, we manufacture self-powered sensors that operate in various sensing modes (d 31 , d 33 , and d 15 ) and tested with tire, shaker and light finger tapping. This work further expands on the potential applications of freeze casting and provides new opportunities for the manufacture of future electronics.
Dielectric elastomers have the capability to be used as transducers for actuation and energy harvesting applications due to their excellent combination of large strain capability (100-400%), rapid response (10 s), high energy density (10-150 kJ m ), low noise, and lightweight nature. However, the dielectric properties of non-polar elastomers such as dielectric permittivity ε , breakdown strength E , and dielectric loss ε ″, need to be enhanced for real world applications. The introduction of polar groups or structures into dielectric elastomers through covalently bonding is an attractive approach to 'intrinsically' induce a permanent polarity to the elastomers, and can eliminate the poor post-processing issues and breakdown strength of extrinsically modified materials, which have often been prepared by incorporation of fillers. This review discusses the chemical methods for modification of dielectric elastomers, such as hydrosilylation, thiol-ene click chemistry, azide click chemistry, and atom transfer radical polymerization. The effects of the type and concentration of polar groups on the dielectric and mechanical properties of the elastomers and their performance in actuation and harvesting systems are discussed. State-of-the-art developments and perspectives of modified dielectric elastomers for deformable energy generators and transducers are provided.
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