This work considers how the properties of hydrogen bonded complexes, X-H· · · Y, are modified by the quantum motion of the shared proton. Using a simple two-diabatic state model Hamiltonian, the analysis of the symmetric case, where the donor (X) and acceptor (Y) have the same proton affinity, is carried out. For quantitative comparisons, a parametrization specific to the O-H· · · O complexes is used. The vibrational energy levels of the one-dimensional ground state adiabatic potential of the model are used to make quantitative comparisons with a vast body of condensed phase data, spanning a donor-acceptor separation (R) range of about 2.4 − 3.0Å, i.e., from strong to weak hydrogen bonds. The position of the proton (which determines the X-H bond length) and its longitudinal vibrational frequency, along with the isotope effects in both are described quantitatively. An analysis of the secondary geometric isotope effect, using a simple extension of the two-state model, yields an improved agreement of the predicted variation with R of frequency isotope effects. The role of bending modes is also considered: their quantum effects compete with those of the stretching mode for weak to moderate Hbond strengths. In spite of the economy in the parametrization of the model used, it offers key insights into the defining features of H-bonds, and semi-quantitatively captures several trends.

We report on the design, fabrication and characterization of silica microtoroid based cavity opto-electromechanical systems (COEMS). Electrodes patterned onto the microtoroid resonators allow for rapid capacitive tuning of the optical whispering gallery mode resonances while maintaining their ultrahigh quality factor, enabling applications such as efficient radio to optical frequency conversion, optical routing and switching applications.

Advances in optomechanics have enabled significant achievements in precision sensing and control of matter, including the detection of gravitational waves and the cooling of mechanical systems to their quantum ground state. Recently, the inherent non-linearity in the optomechanical interaction has been harnessed to explore synchronization effects, including the spontaneous locking of an oscillator to a reference injection signal delivered via the optical field. Here, we present the first demonstration of a radiation-pressure driven optomechanical system locking to an inertial drive, with actuation provided by an integrated electrical interface. We use the injection signal to suppress drift in the optomechanical oscillation frequency, strongly reducing phase noise by over 55 dBc/Hz at 2 Hz offset. We further employ the injection tone to tune the oscillation frequency by more than 2 million times its narrowed linewidth. In addition, we uncover previously unreported synchronization dynamics, enabled by the independence of the inertial drive from the optical drive field. Finally, we show that our approach may enable control of the optomechanical gain competition between different mechanical modes of a single resonator. The electrical interface allows enhanced scalability for future applications involving arrays of injection-locked precision sensors.

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