Photoswitchable organic molecules can undergo reversible structural changes with an external light stimulus. These optically controlled molecules have been used in the development of "smart" polymers, optical writing of grating films, and even controllable in-vivo drug release. Being the simplest class of photoswitches in terms of structure, azobenzenes have become the most ubiquitous, well-characterized, and implemented organic molecular switch. Given their predictable response, they are ideally suited to create an all-optically controlled switch. However, fabricating a monolithic optical device comprised solely from azobenzene while maintaining the photoswitching functionality is challenging. In this work, we combine integrated photonics with optically switchable organic molecules to create an optically controlled integrated device. A silica toroidal resonant cavity is functionalized with a monolayer of an azobenzene derivative.After functionalization, the loaded cavity Q is above 10 5 . When 450 nm light is coupled into cavity resonance, the azobenzene isomerizes from trans-isomer to cis-isomer, inducing a refractive index change.Because the resonant wavelength of the cavity is governed by the index, the resonant wavelength changes in parallel. At the probe wavelength of 1300 nm, the wavelength shift is determined by the duration and intensity of the 450 nm light and the density of azobenzene functional groups on the device surface, providing multiple control mechanisms. Using this photoswitchable device, resonance frequency tuning as far as sixty percent of the cavity's free spectral range in the near-IR is demonstrated. The kinetics of the * Both authors contributed equally. a) Corresponding author: armani@usc.eduOptical resonant cavities are a fundamental element of on-chip integrated optical circuits, serving as amplifiers, filters, and buffers.[1-7] These devices have two key features that differentiate them from other components: the ability to isolate and to store pre-defined or resonant wavelengths (λo). In many cases, it is desirable to change the λo, for example, tuning an add-drop filter or encoding an optical signal. Because the λo is governed, in part, by the device refractive index, a common strategy is to leverage the electro-optic effect.[8-10] However, many optical cavities are fabricated from materials like silica with low to negligible electro-optic coefficients. Additionally, while the electro-optic effect can achieve fast tuning over small wavelength ranges, performing large shifts, comparable to the free spectral range of the cavity is challenging. Recent efforts have explored using the thermo-optic effect or the photo-acoustic effect to accomplish larger range tuning. [11][12][13][14][15] However, these control mechanisms are susceptible to cross-talk with adjacent optical components, thus, decreasing the density of the optical circuit.An alternative strategy can be found in photoswitchable or light-triggerable organic materials. This emerging class of materials has rapidly gained promin...