Covalent mechanophores
display the cleavage of a weak covalent
bond when a sufficiently high mechanical force is applied. Three different
covalent bond breaking mechanisms have been documented thus far, including
concerted, homolytic, and heterolytic scission. Motifs that display
heterolytic cleavage typically separate according to non-scissile
reaction pathways that afford zwitterions. Here, we report a new mechanochromic
triarylmethane mechanophore, which dissociates according to a scissile
heterolytic pathway and displays a pronounced mechanochromic response.
The mechanophore was equipped with two styrenylic handles that allowed
its incorporation as a cross-linker into poly(N,N-dimethylacrylamide) and poly(methyl acrylate-co-2-hydroxyethyl acrylate) networks. These materials are
originally colorless, but compression or tensile deformation renders
the materials colored. By combining tensile testing and in
situ transmittance measurements, we show that this effect
is related to scissile cleavage leading to colored triarylmethane
carbocations.
Strongly electric fish use gradients of ions within their bodies to generate stunning external electrical discharges; the most powerful of these organisms, the Atlantic torpedo ray, can produce pulses of over 1 kW from its electric organs. Despite extensive study of this phenomenon in nature, the development of artificial power generation schemes based on ion gradients for portable, wearable, or implantable human use has remained out of reach. Previously, an artificial electric organ inspired by the electric eel demonstrated that electricity generated from ion gradients within stacked hydrogels can exceed 100 V. The current of this power source, however, was too low to power standard electronics. Here, an artificial electric organ inspired by the unique morphologies of torpedo rays for maximal current output is introduced. This power source uses a hybrid material of hydrogel‐infused paper to create, organize, and reconfigure stacks of thin, arbitrarily large gel films in series and in parallel. The resulting increase in electrical power by almost two orders of magnitude compared to the original eel‐inspired design makes it possible to power electronic devices and establishes that biology's mechanism of generating significant electrical power can now be realized from benign and soft materials in a portable size.
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