Superpositioning of negative dc bias in dual-frequency capacitively coupled plasmas (dc-superposed (DS)-CCP) was realized for the selective etching of carbon-doped silicon oxide (SiOCH) films over carbon-doped amorphous silicon (SiC) films, while the dc bias exceeded about −800 V. When a dc bias of −1200 V was superposed on 60 MHz VHF power on the top electrode opposed to a wafer on the bottom electrode biased with 13.56 MHz power, a selectivity of above 50 for SiOCH over SiC was obtained. From characterization of the plasma density and various chemical species in the gaseous phase, such as CF2, CF and atomic N, the density of CF2 significantly decreased with the application of dc bias ranging from −800 to −1200 V. This indicated that CF2 radicals were consumed at the surface of the counter electrode which was made of silicon. The bulk densities of the species including CF2 were decreased, especially due to excess surface loss caused by the bombardment of highly energetic ions accelerated by the superposed dc bias, as well as the rf sheath for the superposition of the negative dc bias. The DS-CCP technology is thus concluded to be indispensable for yielding highly selective etching of SiOCH over SiC.
We performed real-time non-contact monitoring of temperatures of a silicon wafer and chamber parts in plasma etching processes using optical fiber-based low-coherence interferometry. The measurements were performed in dual-frequency capacitively coupled Ar/C4F8/O2 plasma processes. The temperature of a 780-µm-thick Si wafer was measured with a deviation of 0.11 K. Comparison between in-situ measurement results of an on-wafer temperature sensor and an optical-fiber type fluorescence temperature sensor confirmed that the low-coherence interferometry had superior performance in monitoring the temperature of the Si wafer in real-time. This method will enable better control of etching performance with improved process reproducibility.
This paper proposes a technique for simultaneously monitoring the thickness of a SiO2 thin film and the temperature of a Si substrate. This technique uses low-coherence interferometry and has the potential to be used for online monitoring of semiconductor manufacturing processes. In low-coherence interferometry, when the optical path length of a layer is shorter than the coherence length of the light source, the two interference at the top and bottom interfaces of the layer overlap each other. In this case the detected peak position of the interference is shifted from the actual interface, resulting in an error in the temperature measurement, since the temperature is derived from the optical path length of the layer. To improve the accuracy of the temperature measurement, the effect of the overlapping interference was compensated by measuring the SiO2 thickness. The thickness of the Si substrate was 750 μm and the thickness of the SiO2 film was varied between 0 and 2 μm. The SiO2 thickness, which is shorter than the coherence length of the light source, was measured from the ratio of interference intensities of two superluminescent diodes (wavelengths: 1.55 and 1.31 μm). The measured ratio corresponded well with the theoretical one for SiO2 film thicknesses between 0 and 2 μm, and the error was less than 25 nm. The Si temperature was measured from the optical path length. In order to compensate for the overlapping interference, the shift in the peak position of the interference at the SiO2/Si interface was estimated from the measurement results of the SiO2 thickness. This improved the accuracy of the temperature measurement from 5.3 to 3.5 °C.
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