Process designs for the continuous recovery of lactic acid from fermentation broth by reactive distillation (esterification and hydrolysis with C1 to C4 alcohols) are developed and optimized to minimize cost. The best designs are qualitatively different for different alcohols because of the differing volatility ranking of reactants and products and the formation of a two-liquid phase zone in some cases. The results suggest that the methanol and butanol processes are the most attractive. The costs of these two processes are similar, and the ranking depends on the payback period. The ethanol and isopropyl alcohol processes are more expensive because an entrainer is required to break the alcohol/water azeotrope.
Plantwide control of processes to purify lactic acid by esterification and subsequent hydrolysis are investigated. Two processes are considered and compared: one using methanol and the other using butanol. The alcohol liberated in the hydrolysis column is recycled to the esterification column, and the water liberated in the esterification column can be re-used in the hydrolysis column, resulting in highly-interconnected process flowsheets. For both processes, designs with one recycle stream (alcohol only) and two recycle streams (alcohol and water) are tested, and for each alcohol and each configuration, both temperature and composition control are tested for all columns (reactive and non-reactive). The results show that processes with only a single recycle stream are somewhat easier to control. For the butanol process, a temperature control structure with only a single composition controller is found to be adequate, while additional composition measurements with constraints on * controller outputs are required for good control of the methanol process. For both processes, responses are more symmetric when temperature control structures are used.
As an alternative to gasoline, bioethanol can be produced from lignocellulosic biomass through hydrolysis using an ionic solution containing zinc chloride (ZnCl2). This method allows for a high yield of glucose from lignocellulose, but entails the removal of ZnCl2 from the hydrolysate using multiple nanofiltration membranes before the fermentation of glucose. This paper presents a mathematical technique for designing such a multistage membrane separation system. The optimization model for the synthesis of membrane networks is based on a superstructure with all feasible interconnections between the membrane units, and consists of mass balances, logical constraints and product specifications. A case study of the separation of a bagasse hydrolysis solution is used to demonstrate the application of the proposed model. Results show that using both types of nanofiltration membranes allows higher ZnCl2 removal ratios at each membrane unit, hence a decrease in the number of membrane units required and a reduction of about 35% in capital cost compared to the cases in which only one membrane type is used. Further analysis is performed to examine the effect of membrane performance on the economics of the separation system.
Summary Since the dual fluidized bed (DFB) system has been increasingly adopted for waste‐to‐energy gasification, a three‐dimensional computational fluid dynamics full‐loop model of a DFB cold flow system has been developed to predict the pressure and sand circulation rate (SCR) under various operating conditions. The pressure data were recorded at 18 specified points along the system height. In addition, the SCRs were determined at the two crucial positions connecting the riser and the gasifier and vice versa. The simulation results were then validated against the experimental data, taking into account the effects of the sand particle size (ds), the air inlet velocity in the riser (v0,riser), and the initial gasifier bed height (h0,gasifier). It could be observed in the riser that the flow structures of the smaller ds(s) were almost scattering patterns, while those of the bigger ones were mainly clusters. Compared with bigger ds(s), more homogeneous pressure distributions in the riser and higher bed expansion in the gasifier were obtained with smaller ones. A compromise between the system performance and pre‐treating cost for the feedstock particle sizes should be considered further to achieve the best system performance. On the other hand, the increases of the v0,riser and the h0,gasifier enhanced the gasifier bed pressure, facilitating the downward sand flow back to the riser via the LLS. Although some minor discrepancies existed between the simulation and experimental data, the predicted tendencies agreed well with the measured ones. It was also found that a system operating with ds = 500 μm, at v0,riser = 4.0 m/s and h0,gasifier = 0.25 m yielded stable flow characteristics and optimal global SCR. Moreover, some unexpected phenomena predicted and verified with the experimental observations could be avoided or minimized using suitable particle sizes of the feedstock and operating parameters. In sum, the better validation results with lower errors than our previous study, the more reasonable air‐sand flow patterns, and the substantial predictions of undesirable problems are the significant improvements of this study, providing valuable information for effectively designing and operating the practical DFB hot flow systems. Novelty Statement This study developed a 3D computational fluid dynamics full‐loop model of a DFB cold flow system for predicting the pressure and sand circulation rates under various operating conditions of particle size, inlet velocity, and initial bed height. The better validation results against the experimental data, the more reasonable air‐sand flow patterns, and the substantial predictions of undesirable problems are the significant improvements of this study, providing helpful information for designing and operating the DFB hot flow gasifiers.
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