A N95 face-piece respirator and a 3M air filter composed of non-woven polypropylene filter material were investigated for their multi-scale microstructure and resulting filtration performance. Filtration mechanisms of each system are found and quantified. Both media showed a gradually decrease of the most penetrating particle size with respect to an increase in face velocity or surface charge density. Increasing the face velocity and porosity dramatically degraded the collection efficiency in the 3M filter rather than in the N95 system. We exploited three-dimensional X-ray tomography to characterize the morphological and geometrical properties of the fiber arrangement and deposition of aerosol on the fiber surface. Tuning the most predominant material parameters to achieve a precedence in lower pressure drop or higher collection efficiency in a specifically captured particle size range is of great requisite to a peculiar application of the filter media.
The coaxial core/shell composite electrospun nanofibers consisting of relaxor ferroelectric P(VDF-TrFE-CTFE) and ferroelectric P(VDF-TrFE) polymers are successfully tailored towards superior structural, mechanical, and electrical properties over the individual polymers. The core/shell-TrFE/CTFE membrane discloses a more prominent mechanical anisotropy between the revolving direction (RD) and cross direction (CD) associated with a higher tensile modulus of 26.9 MPa and good strength-ductility balance, beneficial from a better degree of nanofiber alignment, the increased density, and C-F bonding. The interfacial coupling between the terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for comparable full-frequency dielectric responses between the core/shell-TrFE/CTFE and pristine terpolymer. Moreover, an impressive piezoelectric coefficient up to 50.5 pm/V is achieved in the core/shell-TrFE/CTFE composite structure. Our findings corroborate the promising approach of coaxial electrospinning in efficiently tuning mechanical and electrical performances of the electrospun core/shell composite nanofiber membranes-based electroactive polymers (EAPs) actuators as artificial muscle implants.
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