Zinc dithiophosphates (ZDDP) have been widely applied in automobile industry for over 70 years as a lubricant additive for wear protection. Tribolayers have been described as blue-and brown-colored layers on surfaces observed by microscopical observation or even bare eye presumably as a consequence of layer thickness or chemical composition. However, the reaction pathways of ZDDP tribolayers are still not yet fully understood. In the present study, the difference between the blue-and brown-colored tribolayers has been revealed by high resolution methods in cylindrical roller thrust bearings at relatively high contact pressures of around 1.92 GPa. After running a FE8 standard bearing test with a normal load of 80 kN and a temperature of 60˝C, said tribolayers could be identified on the bearing surfaces. By using Raman spectroscopy, it could be shown that the blue-colored layers are enriched by FeS and ZnS whereas the brown-colored layers show a significant amount of Fe 3 O 4 . This is an interesting finding as it clearly shows a correlation between the color appearance of the films and the chemical composition besides potential film thickness variations. Finally, transmission electron microscopy verified the amorphous nature of the formed tribolayer which is in a good agreement with literature.

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Abstract:Laser surface texturing has been successfully applied in the past to various machine elements in order to improve their tribological performance. In this study, direct laser interference patterning was used to produce periodic cross-like surface patterns on commercial cylinder roller bearings. The wear behavior of as-patterned bearings was studied by a modified FE8 test rig under boundary lubrication. A mineral oil (ISO VG 100) as a base oil additivated with 0.02 wt % zinc dialkyldithiophosphate (ZDDP) was used for the tribological tests which were performed under a Hertzian pressure of 1.92 GPa and maintained at 80 • C and 20 rpm for 2 h. The laser-patterned bearings showed a significantly reduced mass loss by two orders of magnitude compared to the unpatterned reference bearings. A closer look at the samples proved the formation of the characteristic blue-colored ZDDP tribofilm on top of the laser-induced topography maximum positions. Due to the higher contact pressure at the laser-induced peaks, the tribofilm formation was preferable at those positions thus protecting against wear. The laser patterns nearly remained unworn compared to the reference samples. A subsequent Raman analysis of the laser-patterned bearings clearly revealed the formation of zinc and iron sulfides as well as phosphates at the peak points.

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Laser surface texturing (LST) has been proven to improve the tribological performance of machine elements. The micro-scale patterns manufactured by LST may act as lubricant reservoirs, thus supplying oil when encountering insufficient lubrication. However, not many studies have investigated the use of LST in the boundary lubrication regime, likely due to concerns of higher contact stresses that can occur with the increasing surface roughness. This study aims to examine the influence of LST on the fatigue lifetime of thrust rolling bearings under boundary lubrication. A series of periodic patterns were produced on the thrust rolling bearings, using two geometrically different designs, namely cross and dimple patterns. Base oil ISO VG 100 mixed with 0.05 wt% P of zinc dialkyldithiophosphate (ZDDP) was supplied. The bearings with cross patterns reduce the wear loss by two orders of magnitude. The patterns not only retain lubricant in the textured pockets but also enhance the formation of an anti-wear tribofilm. The tribofilm generation may be improved by the higher contact stresses that occur when using the textured surface. Therefore, in contrast to the negative concerns, the ball bearings with cross patterns were instead found to increase the fatigue life by a factor of three.