In this article, we analyse materials and techniques used in OLED manufacturing in terms of sustainability and highlight upcoming trends which are supposed to further enhance this technologies sustainability.
The substitution of rare metals such as iridium and platinum in light-emitting materials is a key step to enable low-cost mass-production of organic light-emitting diodes (OLEDs). Here, it is demonstrated that using a solution-processed, fully bridged dinuclear Cu(I)-complex can yield very high efficiencies. An optimized device gives a maximum external quantum efficiency of 23 ± 1% (73 ± 2 cd A(-1) ).
This paper presents new experimental results on a polymer light-emitting diode based visible light communications system. For the first time we demonstrate a 10 Mb/s link based on the on-off keying data format with real time equalization on a field programmable gate array. The 10 Mb/s transmission speed is available at a bit error rate less than 4.6 × 10(-3), which is the limit for forward error correction. At a BER of 10(-6) a transmission speed of 7 Mb/s is readily achievable.
The development of iridium-free, yet efficient emitters with thermally activated delayed fluorescence (TADF) was an important step towards mass production of organic light-emitting diodes (OLEDs). Progress is currently impeded by the low solubility and low chemical stability of the materials. Herein, we present a Cu -based TADF emitter that is sufficiently chemically stable under ambient conditions and can be processed by printing techniques. The solubility is drastically enhanced (to 100 g L ) in relevant printing solvents. The integrity of the complex is preserved in solution, as was demonstrated by X-ray absorption spectroscopy and other techniques. In addition, it was found that the optoelectronic properties are not affected even when partly processing under ambient conditions. As a highlight, we present a TADF-based OLED device that reached an efficiency of 11±2 % external quantum efficiency (EQE).
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