The
development of acetone gas sensors is desirable but challenging for
both air quality monitoring and medical diagnosis. Herein, starting
from bimetallic In/Ga metal–organic frameworks (MOFs) (MIL-68
(In/Ga)), a facile strategy is proposed to couple with zinc ions to
design In/Ga oxide (IGO)@ZnO core–shell nanotubes for efficient
acetone detection. In such a heterostructure, tiny ZnO nanoparticles
are closely decorated on IGO nanotubes, which is beneficial to enlarge
the specific surface area and create rich oxygen vacancies and heterojunction
interfaces. Benefiting from the structural merits and synergetic effects,
the IGO@ZnO-based gas sensor exhibits a low detection limitation (200
ppb), a high response, good linearity relationship between the sensing
responses and wide testing acetone concentrations, and fast response
and recovery time (6.8/6.1 s) with good selectivity and stability.
These sensing performances strongly indicate the practical application
to quantitatively detect acetone.
Here,
we synthesized bimetallic Ni/Fe MOFs using 2-aminoterephthalic
acid (NH2–BDC) as ligand by a facile hydrothermal
route. After calcination, spindle-like Ni/Fe MOFs are transferred
into porous NiFe2O4 nanorods. The resulting
NiFe2O4 based sensor shows an excellent sensitivity
(almost 60–500 ppm), good selectivity against various VOCs,
and a good linearity in wide concentration and stability for toluene
detection. Three major aspects of good catalytic activity, large surface
area, and porous structures of NiFe2O4 are significantly
attributed to the excellent gas-sensing performances. These findings
demonstrate a new perspective of bimetallic Ni/Fe MOFs-derived NiFe2O4 for the promising application in toluene gas
sensor.
Toluene is extensively used in many industrial products, which needs to be effectively detected by sensitive gas sensors even at low-ppm-level concentrations. Here, NiFe2O4 nano-octahedrons were calcinated from NiFe-bimetallic metal-organic framework (MOFs) octahedrons synthesized by a facile refluxing method. The co-existence of p-Phthalic acid (PTA) and 3,3-diaminobenzidine (DAB) promotes the formation of smooth NiFe-bimetallic MOFs octahedrons. After subsequent thermal treatment, a big weight loss (about 85%) transformed NiFe2O4 nanoparticles (30 nm) into NiFe2O4 porous nano-octahedrons with hollow interiors. The NiFe2O4 nano-octahedron based sensor exhibited excellent gas sensing properties for toluene with a nice stability, fast response, and recovery time (25 s/40 s to 100 ppm toluene), and a lower detection limitation (1 ppm) at 260 °C. The excellent toluene-sensing properties can not only be derived from the hollow interiors combined with porous nano-octahedrons to favor the diffusion of gas molecules, but also from the efficient catalytic activity of NiFe2O4 nanoparticles.
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