Refined
coal pitch is a recognized precursor
to produce high-quality needle coke with its higher aromaticity, lower
ash content, and a relatively narrow distribution of molecular weight.
The aromatic index (f
a) of refined coal
pitch is one of the key roles in the production of high-quality needle
coke. In order to a detailed study on the effects of f
a on the microstructure and properties of needle coke,
9 kinds of refined coal pitches with varied f
a were used as the raw materials to produce needle coke in
this study. Briefly, 1H NMR was used to calculate the f
a of each refined coal pitch. Polarizing microscope,
scanning electron microscopy, microstrength tester, X-ray diffraction,
Raman spectrum, and curve-fitted methods have been used to quantitatively
examine the microstructure and microstrength of each needle coke.
The results have shown that the refined coal pitch with the f
a of 0.95–0.98 was the best precursor
to produce high-quality needle coke.
Refined coal tar
pitch is considered as a promising material for
the production of needle coke owing to its excellent physical–chemical
properties. It was generally accepted that the basic properties of
refined coal pitch played a vital role in affecting the resulting
quality of the derived needle coke during the delayed coking process.
Our previous research showed that an f
a of 0.95–0.98 of refined coal pitch was optimal and produced
needle coke of the highest quality. What is more, we found that the
contents of β resin in refined pitch were also important to
the properties (microstructure, microstrength, and true density) of
the derived needle coke. Therefore, the effects of the contents of
β resin on the properties of needle coke were investigated thoroughly,
and eight types of refined coal pitch (the f
a range from 0.9621 to 0.9725) with varied contents of β
resin were employed as the precursors of needle coke. The techniques
of proton nuclear magnetic resonance and gel permeation chromatography
were utilized to determine the f
a and
molecular weight of each refined coal pitch, respectively. Microstructures
(optical microstructure and surface morphology) have been analyzed
by polarizing microscopy and scanning electron microscopy, separately.
X-ray diffraction, Raman spectra, and curve-fitting enabled the quantitative
examination of the microcrystalline structure. What is more, the microstrength
and true density of each needle coke have also been examined in this
study. It was concluded that a β resin content of 13–16%
in the refined coal pitch achieved the best results and was optimal
for needle coke production.
High-temperature
coal tar pitch is often used to produce high-quality needle coke.
Its basic properties [such as f
a value,
β resin, and quinoline insoluble (QI) content] significantly
affect the quality of the resulting needle coke. Refined pitch with f
a and β-resin values in the 0.95–0.98
and 13–16% ranges, respectively, is considered an excellent
raw material for this purpose. The influence of QI content on the
characteristics of coal-based needle coke is still not fully clarified
in the literature. To analyze how QI content affects coal-based needle
coke properties, this work used 10 different kinds of coal tar pitch
(refined from the same source) with different QI contents for the
needle coke production. We thoroughly analyzed optical microstructure
and crystalline sizes, surface morphology and microstrength, true
density, and coefficient of thermal expansion (CTE) of the resulting
products. The high-temperature coal tar pitch with the QI content
of <0.8% was a preferable raw material to obtain superior needle
coke; it possessed higher density and microstrength, lower CTE, and
graphitized more easily than cokes with other parameters.
Refined polymerized pitch (RPP) is a by-product from the production of mesocarbon microbeads (MCMB). In order to understand the effects of an air oxidation treatment on the microstructure of the synthesized pitch coke, oxidized and polymerized pitch (prepared by oxidation in air with RPP as the raw material) has been used as the raw material to produce pitch coke. The microstructure of as-prepared pitch coke was determined using optical microscopy, scanning electron microscopy, XRD, and Raman spectroscopy and was combined with a curve-fitting method. The true density and micro-strength of each pitch coke was also investigated in this study. The results showed that the oxidation of RPP in air caused a mosaic structure with amorphous carbon in the derived pitch coke. In addition, the micro-strength of the derived pitch coke improved from 65% to 77%, and the amorphous carbon content also increased from 10.41% to 14.59% after the air oxidation treatment. Therefore, the air oxidation treatment of RPP took place before liquid-carbonization and was a feasible method for the production of hard carbon. K E Y W O R D S micro-strength, microstructure, Oxidized polymerized pitch, pitch coke, true density 1 | INTRODUCTION As a type of polycyclic aromatic carbonaceous compounds with excellent physical and chemical properties, coal pitch has attracted more attention in varied fields such as: metallurgy, the chemical industry, machining, and construction. 1-4 In recent years, the efficient and high value-added utilization of coal pitch has been a common research topic. 5-8 Coal pitch is usually divided into four categories in literature: high-temperature coal
Medium–low temperature coal tar pitch (MLP) is a type of aromatic carbonaceous material obtained by the low temperature distillation of low rank coal, and is considered as a desirable raw material for the production of artificial carbon/graphite material. The thermal conversion behaviors of MLP during the liquid‐phase carbonization process were analyzed in detail in this study. Further, the changes of molecular structure and carbon microcrystalline structure of MLP and liquid‐phase carbonization products derived from it were quantitatively investigated by optical microscopy, fourier transform infrared spectroscopy, Raman spectroscopy, X‐ray diffraction, and curve‐fitting method. Results showed that both branched chain and the contents of C=O functional groups in the MLP played a key role in the reaction reactivity. Moreover, temperature of 450 °C was found to be a rapid changing temperature point on the enhancement of thermal conversion of MLP. The stacking height (Lc), parallel layers (N), average number of aromatic rings in each layer (n), ratio of ‘impurity’ structure (RI), ratio of amorphous carbon structure (RAC), ratio of graphite carbon structure (RGC), and ratio of defects graphite carbon structure (RDGC) exhibited a significant change with the improvement of liquid‐phase carbonization temperature.
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