Efficient photo- and piezoelectric-induced molecular oxygen activation are both achieved by macroscopic polarization enhancement on a noncentrosymmetric piezoelectric semiconductor BiOIO . The replacement of V ions for I in IO polyhedra gives rise to strengthened macroscopic polarization of BiOIO , which facilitates the charge separation in the photocatalytic and piezoelectric catalytic process, and renders largely promoted photo- and piezoelectric induced reactive oxygen species (ROS) evolution, such as superoxide radicals ( O ) and hydroxyl radicals ( OH). This work advances piezoelectricity as a new route to efficient ROS generation, and also discloses macroscopic polarization engineering on improvement of multi-responsive catalysis.
Non-centrosymmetric polar Bi2O2(OH)(NO3) with a rational band structure and {001} active exposing facets is developed as a robust layered photocatalyst for photooxidative diverse industrial contaminants and pharmaceuticals.
This tutorial review focuses on aqueous slurries of dispersed engineered nanoparticles (ENPs) used in chemical mechanical planarization (CMP) for polishing wafers during manufacturing of semiconductors.
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