There is a growing shift from liquid electrolytes toward solid polymer electrolytes, in energy storage devices, due to the many advantages of the latter such as enhanced safety, flexibility, and manufacturability. The main issue with polymer electrolytes is their lower ionic conductivity compared to that of liquid electrolytes. Nanoscale fillers such as silica and alumina nanoparticles are known to enhance the ionic conductivity of polymer electrolytes. Although carbon nanotubes have been used as fillers for polymers in various applications, they have not yet been used in polymer electrolytes as they are conductive and can pose the risk of electrical shorting. In this study, we show that nanotubes can be packaged within insulating clay layers to form effective 3D nanofillers. We show that such hybrid nanofillers increase the lithium ion conductivity of PEO electrolyte by almost 2 orders of magnitude. Furthermore, significant improvement in mechanical properties were observed where only 5 wt % addition of the filler led to 160% increase in the tensile strength of the polymer. This new approach of embedding conducting-insulating hybrid nanofillers could lead to the development of a new generation of polymer nanocomposite electrolytes with high ion conductivity and improved mechanical properties.
Through structure design, 3D printing enables the fabrication of mechanically durable superhydrophobic membranes with an ordered porous structure for oil–water separation.
In this work, a great synergistic effect of 2D clay platelets and 1D carbon nanotubes (CNTs) on reinforcing chitosan matrix has been observed for the first time. With incorporation of 3 wt % clay and 0.4 wt % CNTs, the tensile strength and Young's modulus of the nanocomposites are significantly improved by about 171 and 124%, respectively, compared with neat chitosan. This could be understood as due to the formation of much jammed fillers network with 1D CNTs and 2D clay platelets combined together, as indicated by rheological measurement. Our work demonstrates a good example for the preparation of high performance polymer nanocomposites by using nanofillers of different dimension together.
Two dimensional graphene oxide (GO) sheets with high surface area and excellent mechanical properties are introduced into a solid polyethylene oxide/lithium salt electrolyte.
Passive daytime radiative cooling (PDRC) involves cooling down an object by simultaneously reflecting sunlight and thermally radiating heat to the cold outer space through the Earth's atmospheric window. However, for practical applications, current PDRC materials are facing unprecedented challenges such as complicated and expensive fabrication approaches and performance degradation arising from surface contamination. Herein, we develop scalable cellulose-fiber-based composites with excellent self-cleaning and self-cooling capabilities, through air-spraying ethanolic poly-(tetrafluoroethylene) (PTFE) microparticle suspensions embedded partially within the microsized pores of the cellulose fiber to form a dual-layered structure with PTFE particles atop the paper. The formed superhydrophobic PTFE coating not only protects the cellulose-fiberbased paper from water wetting and dust contamination for real-life applications but also reinforces its solar reflectivity by sunlight backscattering. It results in a subambient cooling performance of 5 °C under a solar irradiance of 834 W/m 2 and a radiative cooling power of 104 W/m 2 under a solar intensity of 671 W/m 2 . The self-cleaning surface of composites maintains their good cooling performance for outdoor applications, and the recyclability of the composites extends their life span after one life cycle. Additionally, dyed cellulose-fiber-based paper can absorb appropriate visible wavelengths to display specific colors and effectively reflect nearinfrared lights to reduce solar heating, which synchronously achieves effective radiative cooling and esthetic varieties.
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