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The slip effects of water flow in hydrophilic and hydrophobic microchannels of 1 and 2 μm depth are examined experimentally. High-precision microchannels were treated chemically to enhance their hydrophilic and hydrophobic properties. The flow rates of pure water at various applied pressure differences for each surface condition were measured using a high-precision flow metering system and compared to a theoretical model that allows for a slip velocity at the solid surface. The slip length was found to vary approximately linearly with the shear rate with values of approximately 30 nm for the flow of water over hydrophobic surfaces at a shear rate of 105 s−1. The existence of slip over the hydrophilic surface remains uncertain, due to the sensitivity of the current analysis to nanometer uncertainties in the channel height.

Enabled by a technology to fabricate well-defined nanogrates over a large area ͑2 ϫ 2 cm 2 ͒, we report the effect of such a surface, in both hydrophilic and hydrophobic conditions, on liquid slip and the corresponding friction reduction in microchannels. The grates are designed to be dense ͑ϳ230 nm pitch͒ but deep ͑ϳ500 nm͒ in order to sustain a large amount of air in the troughs when the grates are hydrophobic, even under pressurized liquid flow conditions ͑e.g., more than 1 bar͒. A noticeable slip ͑i.e., slip length of 100-200 nm, corresponding to 20%-30% reduction of pressure drop in a ϳ3 m high channel͒ is observed for water flowing parallel over the hydrophobic nanogrates; this is believed to be an "effective" slip generated by the nanostrips of air in the grate troughs under the liquid. The effective slip is clearer and larger in flows parallel to the nanograting patterns than in transverse, suggesting that the nanograted superhydrophobic surfaces would not only reduce friction in liquid flows under pressure but also enable directional control of the slip. This paper is the first to use nanoscale grating patterns and to measure their effect on liquid flows in microchannels.

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Cells in their native microenvironment interact with three-dimensional (3D) nanofeatures.Despite many reports on the effects of substrate nanotopography on cells, the independent effect of 3D parameters has not been investigated. Recent advances in nanofabrication for precise control of nanostructure pattern, periodicity, shape, and height enabled this systematic study of cell interactions with 3D nanotopographies. Two distinct nanopatterns (posts and grates) with varying three-dimensionalities (50-600 nm in nanostructure height) were created, while maintaining the pattern periodicity (230 nm in pitch) and tip shape (needle-or blade-like sharp tips). Human foreskin fibroblasts exhibited significantly smaller cell size and lower proliferation on needle-like nanoposts, and enhanced elongation with alignment on blade-like nanogrates.These phenomena became more pronounced as the nanotopographical three-dimensionality (structural height) increased. The nanopost and nanograte architectures provided the distinct contact guidance for both filopodia extension and the formation of adhesion molecules complex, which was believed to lead to the unique cell behaviors observed.

In this paper, we report the measurement of skin friction drag on superhydrophobic-coated flat plates in high Reynolds (Re) number boundary layer flows, using a high-speed towing tank system. Aluminum flat plates with a large area (4 feet × 2 feet, 3/8 in. thick) and sharpened leading/trailing edges (1 in. long) were prepared as a boundary layer flow model. Spray coating of hydrophobic nanoparticles was applied to make two different types of superhydrophobic coatings: one with low contact angle and high contact angle hysteresis, and the other with high contact angle and low contact angle hysteresis. Skin friction drag of the superhydrophobic plates was measured in the flow speed up to 30 ft/s to cover transition and turbulent flow regimes (105 < ReL < 107), and was compared to that of an uncoated bare aluminum plate. A significant drag reduction was observed on the superhydrophobic plate with high contact angle and low contact angle hysteresis up to ∼30% in transition regime (105 < ReL < 106), which is attributed to the shear-reducing air layer entrapped on the superhydrophobic surface. However, in fully turbulence regime (106 < ReL < 107), an increase of drag was observed, which is ascribed to the morphology of the surface air layer and its depletion by high shear flow. The texture of superhydrophobic coatings led to form a rugged morphology of the entrapped air layer, which would behave like microscale roughness to the liquid flow and offset the drag-reducing effects in the turbulent flow. Moreover, when the superhydrophobic coating became wet due to the removal of air by high shear at the boundary, it would amplify the surface roughness of solid wall and increase the drag in the turbulent flow. The results illustrate that drag reduction is not solely dependent on the superhydrophobicity of a surface (e.g., contact angle and air fraction), but the morphology and stability of the surface air layer are also critical for the effective drag reduction using superhydrophobic surfaces, especially in high Re number turbulent flow regimes.

This study explores how surface morphology affects the dynamics of contact line depinning of an evaporating sessile droplet on micropillared superhydrophobic surfaces. The result shows that neither a liquid-solid contact area nor an apparent contact line is a critical physical parameter to determine the depinning force. The configuration of a contact line on a superhydrophobic surface is multimodal, composed of both two phases (liquid and air) and three phases (liquid, solid, and air). The multimodal state is dynamically altered when a droplet recedes. The maximal three-phase contact line attainable along the actual droplet boundary is found to be a direct and linear parameter that decides the depinning force on the superhydrophobic surface.