We report on fabrication of novel field-effect transistors (FETs) based on transition metal dichalcogenides. The unique structure of single crystals of these layered inorganic semiconductors enables fabrication of FETs with intrinsically low field-effect threshold and high charge carrier mobility, comparable to that in the best single-crystal Si FETs (up to 500 cm 2 /Vs for the p-type conductivity in the WSe 2 -based FETs at room temperature). These novel FETs demonstrate ambipolar operation. Owing to mechanical flexibility, they hold potential for applications in "flexible" electronics.In modern electronics, the requirements to field-effect transistors are stringent and often contradictory: e.g., for many applications, a combination of high charge carrier mobility (µ) and mechanical flexibility is desirable. Neither of the developed FETs satisfies these requirements. For example, the process of fabrication of silicon FETs with a relatively high µ ≤ 500 cm 2 /Vs [1,2] is incompatible with flexible substrates. The organic-based FETs, that provide basis for flexible electronics [3,4,5], are notoriously known for their low µ. Although several
Inelastic neutron scattering was used to systematically investigate the spinwave excitations (magnons) in ferromagnetic manganese perovskites. In spite of the large differences in the Curie temperatures (T C s) of different manganites, their low-temperature spin waves were found to have very similar dispersions with the zone boundary magnon softening. From the wavevector dependence of the magnon lifetime effects and its correlation with the dispersions of the optical phonon modes, we argue that a strong magnetoelastic coupling is responsible for the observed low temperature anomalous spin dynamical behavior of the manganites.
Elastic and inelastic neutron scattering was used to study two ferromagnetic manganites A 1−x B x MnO 3 (x ≈ 0.3) with T c =197.9 K and 300.9 K. The spin dynamical behavior of these is similar at low temperatures, but drastically different at temperatures around T c . While the formation of spin clusters of size (∼ 20Å) dominates the spin dynamics of the 197.9 K sample close to T c , the paramagnetic to ferromagnetic transition for the 300.9 K sample is more conventional. These results, combined with seemingly inconsistent earlier reports, reveal clear systematics in the spin dynamics of the manganites.
Superconductivity in electron-doped C60 was first observed almost ten years ago. The metallic state and superconductivity result from the transfer of electrons from alkaline or alkaline-earth ions to the C60 molecule, which is known to be a strong electron acceptor. For this reason, it is very difficult to remove electrons from C60--yet one might expect to see superconductivity at higher temperatures in hole-doped than in electron-doped C60, because of the higher density of electronic states in the valence band than in the conduction band. We have used the technique of gate-induced doping in a field-effect transistor configuration to introduce significant densities of holes into C60. We observe superconductivity over an extended range of hole density, with a smoothly varying transition temperature Tc that peaks at 52 K. By comparison with the well established dependence of Tc on the lattice parameter in electron-doped C60, we anticipate that Tc values significantly in excess of 100 K should be achievable in a suitably expanded, hole-doped C60 lattice.
Copper phthalocyanine (Cu-Pc) single crystals were grown by physical vapor
transport and field effect transistors (FETs) on the surface of these crystals
were prepared. These FETs function as p-channel accumulation-mode devices.
Charge carrier mobilities of up to 1 cm2/Vs combined with a low field-effect
threshold were obtained. These remarkable FET-characteristics, along with the
highly stable chemical nature of Cu-Pc make it an attractive candidate for
device applications
C60 single crystals have been intercalated with CHCl3 and CHBr3 in order to expand the lattice. High densities of electrons and holes have been induced by gate doping in a field-effect transistor geometry. At low temperatures, the material turns superconducting with a maximum transition temperature of 117 K in hole-doped C60/CHBr3. The increasing spacing between the C60 molecules follows the general trend of alkali metal-doped C60 and suggests routes to even higher transition temperatures.
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