In this paper we describe the capabilities for texture measurements of the new neutron time-of-flight diffractometer HIPPO at the Los Alamos Neutron Science Center. The orientation distribution function (ODF) is extracted from multiple neutron time-of-flight histograms using the full-pattern analysis first described by Rietveld. Both, the well-established description of the ODF using spherical harmonics functions and the WIMV method, more recently introduced for the analysis of time-of-flight data, are available to routinely derive the ODF from HIPPO data. At ambient conditions, total count time of less than one hour is ample to collect sufficient data for texture analysis in most cases. The large sample throughput for texture measurements at ambient conditions possible with HIPPO requires a robust and reliable, semi-automated data analysis. HIPPO’s unique capabilities to measure large quantities of ambient condition samples and to measure texture at temperature and uni-axial stress are described. Examples for all types of texture measurements are given
High-resolution elemental mapping in a transmission electron microscope shows that the residual silver in dealloying-made nanoporous gold (NPG) is aggregated in nanoscale clusters. Kinetic Monte Carlo simulation confirms that these regions are buried relics of the master alloy that have never been exposed to corrosion. The surface of as-dealloyed NPG is covered by at least one atomic monolayer of nearly pure gold. The preferential location of silver in the bulk is relevant when interfaces control the material's function, as in catalysis and sensing. Annealing in air homogenizes the alloy by surface diffusion. IMPACT STATEMENT The residual silver which is typically found in nanoporous gold made by dealloying is localized in clusters that are relics of the original master alloy which have evaded corrosion.
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