César Augusto Brüning scite author profile

An efficient and environmentally benign synthesis of 3-organoselenylchromenones was accomplished via ironA C H T U N G T R E N N U N G (III) chloride/diorganyl diselenidespromoted intramolecular 6-endo-dig cyclization of alkynyl aryl ketone derivatives. The cyclization reactions proceeded cleanly under mild reaction conditions, and the desired chromenone derivatives were smoothly isolated in good yields. The methodology proved to be highly regioselective, giving only the six-membered regioisomers and was carried out using ironA C H T U N G T R E N N U N G (III) chloride/diorganyl diselenide at room temperature and under ambient atmosphere, which could be considered an economic and eco-friendly protocol.

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Diphenyl diselenide ameliorates behavioral and oxidative parameters in an animal model of mania induced by ouabain

Brüning

Prigol

Luchese

et al. 2012

Progress in Neuro-Psychopharmacology and Biological Psychiatry

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César Augusto Brüning

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Iron(III) Chloride/Diorganyl Diselenides‐Promoted Regioselective Cyclization of Alkynyl Aryl Ketones: Synthesis of 3‐Organoselenyl Chromenones under Ambient Atmosphere

Diphenyl diselenide ameliorates behavioral and oxidative parameters in an animal model of mania induced by ouabain

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