Varying the amounts of silicon and carbon, different composites have been prepared by ball milling of Si, Ni 3.4 Sn 4 , Al and C. Silicon and carbon contents are varied from 10 to 30 wt.% Si, and 0 to 20 wt.% C. The microstructural and electrochemical properties of the composites have been investigated by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and electrochemical galvanostatic cycling up to 1000 cycles. Impact of silicon and carbon contents on the phase occurrence, electrochemical capacity and cycle-life are compared and discussed. For C-content comprised between 9 and 13 wt.% and Si-content 20 wt.%, Si nanoparticles are embedded in a Ni 3.4 Sn 4 -Al-C matrix which is chemically homogeneous at the micrometric scale. For other carbon contents and low Si-amount (10 wt.%), no homogeneous matrix is formed around Si nanoparticles. When homogenous matrix is formed, both Ni 3 Sn 4 and Si participate to the reversible lithiation mechanism, whereas no reaction between Ni 3 Sn 4 and Li is observed for no homogenous matrix. Moreover, best cycle-life performances are obtained when Si nanoparticles are embedded in a homogenous matrix. Composites with carbon in the 9-13 wt.% range and 20 wt.% silicon lead to the best balance between capacity and life duration upon cycling. This work experimentally demonstrates that embedding Si in an intermetallic/carbon matrix allows to efficiently accommodate Si volume changes on cycling to ensure long cycle-life.
The electrochemical behavior of hydride‐forming A2B7 alloys (Y2Ni7, LaSmNi7, and Gd2Ni7) is investigated in KOH solution. The evolution of the material performance is shown to strongly depend on the A elements. Electrochemical impedance spectroscopy (EIS), SEM observations, XRD, and Raman spectroscopy showed that Y2Ni7 is mainly sensitive to calendar corrosion and decrepitation, whereas LaSmNi7 and Gd2Ni7 are sensitive to the concomitant effect of both cycling and calendar corrosion. It is also shown that the capacity loss of Gd2Ni7 can be ascribed to amorphization on cycling, which is not the case for Y2Ni7. The formation of both an thin oxide film (a few tens of nanometers thick) at the material surface, measured by EIS, and the dissolution products formed during long‐term immersion, analyzed by Raman spectroscopy, is in agreement with the decrease in material activity evaluated by EIS during cycling at different depths of charge.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.