The dosage of a collector is an important factor that determines the efficiency of a froth flotation process. The representative sample of the carbonatitic Palabora copper ore ground 45 % passing 75 lm was froth-floated with sodium isobutyl xanthate (SIBX) collector at 60, 70, 80, 90 and 100 g/t dosages. The concentrates and tails were dried and analysed. The results obtained showed that the highest recovery of 85.18 % with a grade of 12.61 % was obtained at the 80 g/t dosage. It was further observed that the copper grade of the concentrate generally decreased with increasing recovery. The particle size distribution analysis of the tailings showed that the froth flotation was most efficient in the fine particle size range 38-75 lm.
The use of mixtures of thiol collectors is reportedly beneficial in sulfide flotation. This is becoming standard practice for many concentrators, but process water recirculation and re-use in flotation circuits may compromise the behaviour of such mixtures owing to changes in physicochemical interactions occurring in the pulp phase as a result of water quality variations. It is expected that changes in the pulp chemistry would in turn affect both the pulp and froth phase phenomena, thereby affecting flotation performance. Thus, this study considers mixtures of thiol collectors, sodium iso-butyl xanthate (SIBX), and sodium di-ethyl dithiophosphate (SEDTP) in degrading water quality. Bench-scale flotation tests were conducted on various molar ratios of the selected thiol collectors under different ionic strengths (0.0242 mol·dm−3 and 0.1212 mol·dm−3) of synthetic plant water. Increasing the ionic strength of synthetic plant water and SEDTP molar ratio resulted in an increase in water, solids, Cu, and Ni recoveries. Cu-Ni grades decreased in increasing SEDTP molar ratios. The highest Cu-Ni grades were obtained in degrading water quality. The increase in water and solids recoveries in increasing SEDTP and ionic strength of plant water is attributed to an increase in froth stability. It can be concluded that the increase in the ionic strength of plant water increased water recoveries and therefore froth stability in parallel with SEDTP’s froth stabilizing effect, thus suggesting an additive interaction on the froth stabilisation effect seen.
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