Volatile organic compound (VOC) detection is a topic of growing interest with applications in diverse fields, ranging from environmental uses to the food or chemical industries. Optical fiber VOC sensors offering new and interesting properties which overcame some of the inconveniences found on traditional gas sensors appeared over two decades ago. Thanks to its minimum invasive nature and the advantages that optical fiber offers such as light weight, passive nature, low attenuation and the possibility of multiplexing, among others, these sensors are a real alternative to electronic ones in electrically noisy environments where electronic sensors cannot operate correctly. In the present work, a classification of these devices has been made according to the sensing mechanism and taking also into account the sensing materials or the different methods of fabrication. In addition, some solutions already implemented for the detection of VOCs using optical fiber sensors will be described with detail.
A low-cost optical fiber sensor to detect volatile organic compounds has been developed. Changes of up to 13.5 dB in the transmitted optical power have been detected with different concentrations of acetone and dichloromethane vapors. The device uses a standard single-mode fiber. The sensing mechanism relies on a vapor-induced refractive index change in a film of a vapochromic material deposited on the thinner region of a tapered fiber.
The measurement of chemical and biomedical parameters can take advantage of the features exclusively offered by optical fibre: passive nature, electromagnetic immunity and chemical stability are some of the most relevant ones. The small dimensions of the fibre generally require that the sensing material be loaded into a supporting matrix whose morphology is adjusted at a nanometric scale. Thanks to the advances in nanotechnology new deposition methods have been developed: they allow reagents from different chemical nature to be embedded into films with a thickness always below a few microns that also show a relevant aspect ratio to ensure a high transduction interface. This review reveals some of the main techniques that are currently been employed to develop this kind of sensors, describing in detail both the resulting supporting matrices as well as the sensing materials used. The main objective is to offer a general view of the state of the art to expose the main challenges and chances that this technology is facing currently.
n is isolated as a powder that is able to detect volatile organic compounds such as acetone even in an aqueous solution. The colour of this vapochromic material changes from bright yellow to white in the presence of different donor solvents such as acetone, methanol or ethanol. For the practical construction of an optical fibre sensor, a sol-gel doped with the vapochromic complex was deposited onto one end of a monomode fibre connected to a coupler. The behaviour of the material was studied at different wavelengths and concentrations of acetone vapours and acetone-water solutions. Changes were detected up to 4 dB in the reflected optical power.
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