The New Zealand sector of the Southern Ocean (NZSSO) has opened about the Indian-Pacific spreading ridge throughout the Cenozoic. Today the NZSSO is characterised by broad zonal belts of antarctic (cold
High‐resolution textural, carbonate, microfossil, and oxygen (δ18O) and carbon (δ13C) stable isotopic analyses are presented for the late Quaternary (isotopic stages 1 to 6) interval of a core at Deep Sea Drilling Project site 594, situated just south of the present Subtropical Convergence in northernmost Subantarctic surface waters on the southern flank of Chatham Rise in the southwest Pacific. Downcore alternations of pelagic and hemipelagic oozes correspond to interglacial and glacial episodes, respectively. Interglacial oozes contain a northern Subantarctic assemblage of planktonic foraminifera, with rare cool subtropical species, while glacial oozes are characterized by species typical of southern(most) Subantarctic waters and include radiolaria with affinity for Antarctic waters. The planktonic δ18O record for the site supports a 3°–6°C temperature change in near‐surface waters between interglacial and glacial stages and indicates that during stage 5e, the near‐surface waters were about 1°C warmer than at present. A pronounced cooling during stage 5d matches that of the Vostok ice core δD record, and negative excursions at the end of stages 2 and 6 support a southern latitude warming preceding northern hemisphere deglaciation. Benthic foraminifera typical of cold intermediate to deep waters can increase dramatically in abundance in the hemipelagic ooze intervals when δ18O results suggest a temperature drop in glacial stage bottom waters of 2°–4°C, possibly a result of upward displacement of Antarctic Intermediate Water by Circumpolar Deep Water at the site. The foraminiferal δ13C records support a reduced influence of North Atlantic Deep Water in the southwest Pacific during glacial stages, when nutrient enhancement occurred in both bottom and surface waters. Despite the pronounced changes between interglacial and glacial conditions inferred at site 594, contributed to by a substantial northward shift by at least 5° of latitude in the position of the Antarctic Convergence south of New Zealand during glacial episodes, we conclude that the Subtropical Convergence remained locked to Chatham Rise (approximately 44°S) throughout stages 1 to 6. Major compression of the intervening belt of Subantarctic water during glacial episodes, and the associated very steep thermal gradients and intensified atmospheric and oceanic circulation patterns that developed in this part of the southwest Pacific, account for the harsh, frigid environment reported for on‐land southern New Zealand at these times.
Analysis of the stratigraphic architecture of the fills of Wanganui, King Country, and eastern Taranaki Basins reveals the occurrence of five 2nd order Late Paleocene and Neogene sequences of tectonic origin. The oldest is the late Eocene-Oligocene Te Kuiti Sequence, followed by the earlyearly Miocene (Otaian) Mahoenui Sequence, followed by the late-early Miocene (Altonian) Mokau Sequence, all three in King Country Basin. The fourth is the middle Miocene to early Pliocene Whangamomona Sequence, and the fifth is the middle Pliocene-Pleistocene Rangitikei Sequence, both represented in the three basins. Higher order sequences (4th, 5th, 6th) with a eustatic origin occur particularly within the Whangamomona and Rangitikei Sequences, particularly those of 6th order with 41 000 yr periodicity.The base of each 2nd order sequence is marked by marine flooding and represents a discrete phase in basin development.
The stable oxygen isotope composition (δ 18 O) of a precipitated carbonate depends mainly on the isotope composition, salinity, and temperature of the host fluid, whereas the stable carbon isotope composition (δ 13 C) reflects the source of CO 2 for precipitation, such as meteoric or sea water, shell dissolution, or various biochemical origins, including microbial oxidation of organic matter and methane. Despite the potentially complex array of controls, natural waters tend to show a characteristic range of isotope values which in turn are mimicked or tracked by the carbonate minerals precipitated from them. Consequently, plots of δ 18 O versus δ 13 C for carbonate materials can help identify their depositional and/or diagenetic environment(s).Here we compile isotope results for about 800 samples of carbonate skeletons, bulk sediments, fossils, limestones, cements, concretions, and veins spanning a range of ages (latest Cretaceous to modern) and locations in temperateregion New Zealand. Despite some overlap, the isotope values for 21 defined categories of carbonate materials tend to group in discrete regions of the δ 18 O-δ 13 C diagram, thereby providing important insights about their origin. New Zealand modern skeletal shelf carbonates plot in a distinctly different field from their tropical counterparts because of their heavier δ 18 O and narrower range of δ 13 C values, in accord with their nontropical bryomol skeletal facies. Cements in New Zealand temperate limestones are predominantly of burial or, more rarely, meteoric origin, but their nontropical heritage based solely on isotope composition becomes blurred and eventually lost as diagenesis proceeds. In common with many other global examples, siderite, calcite, and dolomite concretions have developed during shallow burial in a range of freshwater to marine depositional settings, the carbon originating mainly from early diagenetic, bacterially mediated reactions involving the decomposition of organic matter in bottom sediments. A summary δ 18 O-δ 13 C diagram showing mean and standarddeviation isotope values for the various New Zealand carbonate categories will form a basis for comparing and interpreting other carbonate materials and deposits.
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