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SUMMARYAging of two kinds of transformer insulation paper in natural ester is compared to that in conventional transformer oil (mineral oil). Sealed aging vessels containing copper, insulation paper (Kraft paper and thermally upgraded paper), and dielectric fluid (mineral oil and natural ester) were aged at 90, 110, and 1308C for 399, 371, and 329 days. Under the same aging condition, both the degree of polymerization (DP) and the leveling-off degree of polymerization (LODP) for natural ester aged paper were higher than the ones for mineral oil aged paper, and the micro surface of natural ester aged paper was destroyed less seriously than that of the mineral oil aged paper. The aging time to reach LODP for natural ester aged paper was only 1/4 to 2/3 of that for mineral oil aged paper. When water content in natural ester for natural ester aged Kraft paper samples reached the maximum, acids concentration in natural ester increased abruptly. Water content in natural ester decreased in the whole aging process for natural ester aged thermally upgraded paper samples. Six physical and chemical mechanisms for the slower aging rate of natural ester aged paper are proposed. Evidence for transesterification between natural ester and paper was presented with infrared spectra instrument. Although the acids in natural ester were far more than in mineral oil, the natural ester can significantly slow the thermal aging of the paper. Three mechanisms of this abnormal phenomenon were presented.

A method is introduced for testing insulators under icing conditions. The method is based on and developed from those described in the standard of IEC60-1, IEC 60507 and IEEE Task Force on Insulator Icing Test Methods, which give instructions to test insulators under pollution. Then, the paper explores the effects of various factors, including ice thickness, pollution severity on the surface of insulators before ice accretion, atmospheric pressure, and shed profiles, on the flashover performance of short samples of two different types of silicone rubber (SIR) composite long rod insulators intended for ultra high voltage (UHV) ac transmission lines. The experiments were carried out in the multi-function artificial climate chamber in the High Voltage and Insulation Technological Laboratory of Chongqing University, China. The experimental results reveal the regularity of the effects of ice thickness, pollution severity and atmospheric pressure on the average flashover voltage of two types of composite insulators. Those can provide reference for the outdoor insulation design for UHV ac transmission lines.Index Terms -UHV, Composite insulator, silicone rubber, icing flashover, low air pressure, outdoor insulation.

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The electrochemical oxidation of methanol has been investigated on underpotentially deposited-ruthenium-modified platinum electrode (upd-Ru/Pt) and on underpotentially deposited-tin-modified platinum electrode (upd-Sn/Pt). The submonolayers of upd-Ru and upd-Sn on a Pt electrode increased the rate of methanol electrooxidation several times as large as that on a pure Pt electrode. The best performance for methanol electrooxidation was obtained on a ternary platinum based catalyst modified by upd-Ru and upd-Sn simultaneously. The influence of the submonolayers of upd-Ru adatoms and upd-Sn adatoms on the oxidation of methanol in acid has been investigated. The effect of Ru on methanol electrooxidation lies on the distribution of Ru adatoms on a Pt surface. It has been shown that as long as the amount of upd-Ru deposits were controlled in a proper range, upd-Ru deposits would enhance the methanol oxidation obtained on a Pt electrode at whichever deposition potential the upd-Ru deposits were obtained. The effects of tin are sensible to the potential range. The enhancement effect of upd-Sn adatoms for the oxidation of methanol will disappear as the electrode potential is beyond a certain value. It is speculated that there exists a synergetic effect on the Pt electrode as adatoms Ru and Sn participate simultaneously in the methanol oxidation.