Three wash techniques, each with 1, 10, or 95% (v/v) ethanol:water were used to measure foliar absorption of14C-glyphosate [N-(phosphonomethyl)glycine],14C-3,6-dichloropicolinic acid, and14C-chlorsulfuron {2-chloro-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] carbonyl] benzenesulfonamide} in Tartary buckwheat [Fagopyrum tataricum(L.) Gaertn. ♯3FAGTA], Canada thistle [Cirsium arvense(L.) Scop. ♯ CIRAR], and barley (Hordeum vulgareL. ‘Galt’). For the herbicides and species tested, the most suitable common procedure for determining absorption consisted of a double or triple rinse with or immersion in 10% ethanol. Wiping the treated leaves with cotton balls moistened with the solvent was much less effective. Efficiency of herbicide removal by a given solvent was not related consistently to solubility of the herbicide in the solvent.
Oat (Avena sativaL. ‘Elgin′) seedlings were treated with combinations of diclofop-methyl {methyl ester of 2-[4-(2,4-dichlorophenoxy)phenoxy] propanoic acid} and 2,4-D amine [dimethylamine salt of (2,4-dichlorophenoxy) acetic acid] or diclofop-methyl and chlorsulfuron {2-chloro-N-[[(4-methoxy-6-methyl-1, 3, 5-triazin-2-yl)amino] carbonyl] benzenesulfonamide} to determine the effect of the added herbicide on diclofop-methyl activity. Diclofop-methyl applied alone at rates of 0.50, 0.75, and 1.00 kg/ha killed the oat plants 14 days after treatment. When 2,4-D amine at 0.74 and 1.11 kg/ha was combined with diclofop-methyl, the phytotoxicity of diclofop-methyl was reduced. An antagonistic interaction between diclofop-methyl and 2,4-D was detected. Chlorsulfuron, applied alone, at 20, 40, or 60 g/ha did not affect the growth of oats. Chlorsulfuron additions did not affect the activity of diclofop-methyl. Diclofop-methyl reduced oat coleoptile elongation. Equimolar concentrations of diclofop-methyl and 2,4-D at or above 1 μM significantly reduced the 2,4-D response. A ten-fold increase of either 2,4-D or diclofop-methyl, above an equimolar concentration of 1 μM, significantly enhanced the effect of the herbicide being increased.
Oat (Avena sativaL. ‘Elgin′) and soybean (Glycine maxL. ‘Evans′) were treated with14C-diclofop-methyl {methyl ester of 2-[4-(2,4-dichlorophenoxy)phenoxy] propionic acid]} or14C-diclofop alone or in combination with 2,4-D [(2,4-dichlorophenoxy)acetic acid] or bentazon [3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide] and14C-2,4-D alone or in combination with diclofop-methyl or diclofop. More radioactivity was recovered in the treatment zone after14C-diclofop-methyl applications, alone or in combination, than after similar14C-diclofop treatments in oat and soybean. Basipetal movement of radioactivity was 4 and 1% and acropetal movement was 1 and 4% in oat and soybean, respectively, regardless of the diphenyl ether treatment or time. Addition of 2,4-D or bentazon did not reduce translocation of radioactivity from14C-diclofop-methyl treatments in either plant species. Basipetal movement of radioactivity from14C-diclofop-methyl was greater than from14C-diclofop in both oat and soybean. The addition of diclofop-methyl or diclofop did not affect the pattern or amount of14C-2,4-D radioactivity translocated. In oats, radioactivity appeared to accumulate within the intercalary meristematic region with14C-2,4-D and14C-diphenyl-ether applications. Diclofop-methyl at 1 kg/ha applied either to an entire oat plant at the three-leaf stage or the apical meristemic region resulted in plant mortality. The extent to which transport contributes to diclofop-methyl efficacy is questioned.
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