Chemical ozone destruction occurs over both polar regions in local winter-spring. In the Antarctic, essentially complete removal of lower-stratospheric ozone currently results in an ozone hole every year, whereas in the Arctic, ozone loss is highly variable and has until now been much more limited. Here we demonstrate that chemical ozone destruction over the Arctic in early 2011 was--for the first time in the observational record--comparable to that in the Antarctic ozone hole. Unusually long-lasting cold conditions in the Arctic lower stratosphere led to persistent enhancement in ozone-destroying forms of chlorine and to unprecedented ozone loss, which exceeded 80 per cent over 18-20 kilometres altitude. Our results show that Arctic ozone holes are possible even with temperatures much milder than those in the Antarctic. We cannot at present predict when such severe Arctic ozone depletion may be matched or exceeded.

Spectral measurements of ultraviolet-B radiation made at Toronto since 1989 indicate that the intensity of light at wavelengths near 300 nanometers has increased by 35 percent per year in winter and 7 percent per year in summer. The wavelength dependence of these trends indicates that the increase is caused by the downward trend in total ozone that was measured at Toronto during the same period. The trend at wavelengths between 320 and 325 nanometers is essentially zero.

Derived Meteorological Products (DMPs, including potential temperature, potential vorticity (PV), equivalent latitude (EqL), horizontal winds and tropopause locations) from several meteorological analyses have been produced for the locations and times of measurements taken by several solar occultation instruments and the Aura Microwave Limb Sounder (MLS). MLS and solar occultation data are analyzed using DMPs to illustrate sampling issues that may affect interpretation and comparison of data sets with diverse sampling patterns and to provide guidance regarding the kinds of studies that benefit most from analyzing satellite data in relation to meteorological conditions using the DMPs. Using EqL or PV as a vortex‐centered coordinate does not alleviate all sampling problems, including those in studies using “vortex averages” of solar occultation data and in analyses of localized features (such as polar stratospheric clouds) and other fields that do not correlate well with PV. Using DMPs to view measurements with respect to their air mass characteristics is particularly valuable in studies of transport of long‐lived trace gases, polar processing in the winter lower stratosphere, and distributions and transport of O3 and other trace gases from the upper troposphere through the lower stratosphere. The comparisons shown here demonstrate good agreement between MLS and solar occultation data for O3, N2O, H2O, HNO3, and HCl; small biases are attributable to sampling effects or are consistent with detailed validation results presented elsewhere in this special section. The DMPs are valuable for many scientific studies and to facilitate validation of noncoincident measurements.

The concentrations of the hydrogen radicals OH and HO2 in the middle and upper troposphere were measured simultaneously with those of NO, O3, CO, H2O, CH4, non-methane hydrocarbons, and with the ultraviolet and visible radiation field. The data allow a direct examination of the processes that produce O3 in this region of the atmosphere. Comparison of the measured concentrations of OH and HO2 with calculations based on their production from water vapor, ozone, and methane demonstrate that these sources are insufficient to explain the observed radical concentrations in the upper troposphere. The photolysis of carbonyl and peroxide compounds transported to this region from the lower troposphere may provide the source of HOx required to sustain the measured abundances of these radical species. The mechanism by which NO affects the production of O3 is also illustrated by the measurements. In the upper tropospheric air masses sampled, the production rate for ozone (determined from the measured concentrations of HO2 and NO) is calculated to be about 1 part per billion by volume each day. This production rate is faster than previously thought and implies that anthropogenic activities that add NO to the upper troposphere, such as biomass burning and aviation, will lead to production of more O3 than expected.