New results are reported from an ongoing international research effort to accurately determine the Avogadro constant by counting the atoms in an isotopically enriched silicon crystal. The surfaces of two 28 Si-enriched spheres were decontaminated and reworked in order to produce an outer surface without metal contamination and improved sphericity. New measurements were then made on these two reconditioned spheres using improved methods and apparatuses. When combined with other recently refined parameter measurements, the Avogadro constant derived from these new results has a value of N A = 6.022 140 76(12) × 10 23 mol -1 . The X-ray crystal density method has thus achieved the target relative standard uncertainty of 2.0 × 10 -8 necessary for the realization of the definition of the new kilogram.
A first order transition from a paramagnetic-austenite phase to a ferromagnetic-martensite phase occurring in off-stoichiometry single crystals of Ni 2 MnGa at 313 K presents unique features due to the multifunctional character of the magnetic shape memory alloy. A remarkable magnetocaloric effect, associated with an entropy change up to ΔS≈−86 J kg−1 K−1 and an adiabatic temperature change ΔT≈2.2 K, accompanied by mechanical strain Δε⩾3% have been observed in samples subjected to changes of the applied magnetic field ΔH=4×106 A∕m (≈5 T). The effects of magnetic field, temperature, and stress on the entropy variationΔS are quantified and compared.
A new single crystal from isotopically enriched silicon was used to determine the Avogadro constant N A by the x-ray-crystal density method. The new crystal, named Si28-23Pr11, has a higher enrichment than the former 'AVO28' crystal allowing a smaller uncertainty of the molar mass determination. Again, two 1 kg spheres were manufactured from this crystal. The crystal and the spheres were measured with improved and new methods. One sphere, Si28kg01a, was measured at NMIJ and PTB with very consistent results. The other sphere, Si28kg01b, was measured only at PTB and yielded nearly the same Avogadro constant value. The mean result for both 1 kg spheres is N A = 6.022 140 526(70) × 10 23 mol −1 with a relative standard uncertainty of 1.2 × 10 −8 . This value deviates from the Avogadro value published in 2015 for the AVO28 crystal by about 3.9(2.1) × 10 −8 . Possible reasons for this difference are discussed and additional measurements are proposed.
In 2011, a discrepancy between the values of the Planck constant measured by counting Si atoms and by comparing mechanical and electrical powers prompted a review, among others, of the measurement of the spacing of 28 Si {220} lattice planes, either to confirm the measured value and its uncertainty or to identify errors. This exercise confirmed the result of the previous measurement and yields the additional value d 220 = 192 014 711.98(34) am having a reduced uncertainty.
The Laser Interferometer Space Antenna (LISA) is a gravitational wave detector, which aims to detect 10−20 strains in the frequency range from 0.1 mHz to 0.1 Hz. It is a constellation of three spacecrafts, an equilateral triangle with side length of m, where interferometry monitors the spacecraft distances. Aberrations and jitter of the wavefront sent by a spacecraft to the next combine to cause a measurement noise. The paper investigates analytically this coupling, including beam clipping and far-field propagation, and develops criteria for the assessment of the wavefront quality. It also gives the results of Monte Carlo simulations of the measurement noise for arbitrary wavefront aberrations and jitters.
An additional value of the Avogadro constant was obtained by counting the atoms in isotopically enriched Si spheres. With respect to the previous determination, the spheres were etched and repolished to eliminate metal contaminations and to improve the roundness. In addition, all the input quantities-molar mass, lattice parameter, mass, and volume-were remeasured aiming at a smaller uncertainty. In order to make the values given in Andreas et al. [Metrologia 48, S1 (2011)] and Azuma et al. [Metrologia 52, 360 (2015)] usable for a least squares adjustment, we report about the estimate of their correlation.
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