The activation of O on metal surfaces is a critical process for heterogeneous catalysis and materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of techniques have given crucial insight into the mechanisms, energetics, and dynamics of O adsorption and dissociation. Here, trends in the activation of O on transition metal surfaces are discussed, and various O adsorption states are described in terms of both electronic structure and geometry. The mechanism and dynamics of O dissociation are also reviewed, including the importance of the spin transition. The reactivity of O and O toward reactant molecules is also briefly discussed in the context of catalysis. The reactivity of a surface toward O generally correlates with the adsorption strength of O, the tendency to oxidize, and the heat of formation of the oxide. Periodic trends can be rationalized in terms of attractive and repulsive interactions with the d-band, such that inert metals tend to feature a full d band that is low energy and has a large spatial overlap with adsorbate states. More open surfaces or undercoordinated defect sites can be much more reactive than close-packed surfaces. Reactions between O and other species tend to be more prevalent than reactions between O and other species, particularly on more reactive surfaces.
Developing active, selective, and energy efficient heterogeneous catalytic processes is key to a sustainable future because heterogeneous catalysis is at the center of the chemicals and energy industries. The design, testing, and implementation of robust and selective heterogeneous catalytic processes based on insights from fundamental studies could have a tremendous positive impact on the world.
Alloys of Ag and small amounts of Pd are promising as bifunctional catalysts, potentially combining the inherent selectivity of the noble Ag with that of the more reactive Pd. Stable PdAg surface alloys are prepared via evaporation of Pd onto Ag(111) at room temperature followed by annealing at 400 K to create a model system. Using this procedure, the most stable form of the surface alloy under vacuum was determined to be a Ag-capped PdAg surface alloy, on the basis of a combination of X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM), and density functional theory (DFT). Extensive roughening of the surface was apparent in STM images, characterized by islands of the Ag/PdAg/Ag(111) alloy of several layers thickness. The roughening is attributed to transport of Ag from the Ag(111) surface into the alloy islands. Within these islands, there is a driving force for Pd to be dispersed, surrounded by Ag, on the basis of DFT modeling. Exposure of these Ag/PdAg/Ag(111) islands to CO (0.5 Torr) at 300 K induces migration of Pd to the surface, driven by the energetic stabilization of the Pd−CO bond based on ambient-pressure XPS. Once the Pd is drawn to the surface by higher pressures of CO at room temperature, it remains stable even under very low CO partial pressures at temperatures of 300 K and below, on the basis of DFT-modeled phase behavior. Exposure to 1 Torr of O 2 at 400 K also causes Pd to resurface, and the resulting structure persists even at low pressures and temperatures below 300 K. These results establish that the state of the PdAg catalyst surface depends strongly on pretreatment and operational conditions. Hence, exposure of an alloy catalyst to CO or O 2 at moderate temperatures and pressures can lead to catalyst activation by bringing Pd to the surface. Furthermore, these results demonstrate that exposure to CO at room temperature, which is often used as a proxy for evaluating the Pd coordination sites available in a catalyst, changes the surface structure. Therefore, the CO vibrational frequencies measured with diffuse-reflectance infrared Fourier-transform spectroscopy (DRIFTS) on PdAg catalyst materials do not necessarily provide information about their working state, and fundamental understanding of the CO-PdAg alloy is crucial.
Selective hydrogenation of α,ß-unsaturated aldehydes to unsaturated alcohols is a challenging class of reactions, yielding valuable intermediates for the production of pharmaceuticals, perfumes, and flavorings. On monometallic heterogeneous catalysts, the formation of the unsaturated alcohols is thermodynamically disfavored over the saturated aldehydes. Hence, new catalysts are required to achieve the desired selectivity. Herein, the literature of three major research areas in catalysis is integrated as a step toward establishing the guidelines for enhancing the selectivity: reactor studies of complex catalyst materials at operating temperature and pressure; surface science studies of crystalline surfaces in ultrahigh vacuum; and first-principles modeling using density functional theory calculations. Aggregate analysis shows that bimetallic and dilute alloy catalysts significantly enhance the selectivity to the unsaturated alcohols compared to monometallic catalysts. This comprehensive review focuses primarily on the role of different metal surfaces as well as the factors that promote the adsorption of the unsaturated aldehyde via its C=O bond, most notably by electronic modification of the surface and formation of the electrophilic sites. Furthermore, challenges, gaps, and opportunities are identified to advance the rational design of efficient catalysts for this class of reactions, including the need for systematic studies of catalytic processes, theoretical modeling of complex materials, and model studies under ambient pressure and temperature.
Properties of mono- and bimetallic metal nanoparticles (NPs) may depend strongly on their compositional, structural (or geometrical) attributes, and their atomic dynamics, all of which can be efficiently described by a partial radial distribution function (PRDF) of metal atoms. For NPs that are several nanometers in size, finite size effects may play a role in determining crystalline order, interatomic distances, and particle shape. Bimetallic NPs may also have different compositional distributions than bulk materials. These factors all render the determination of PRDFs challenging. Here extended X-ray absorption fine structure (EXAFS) spectroscopy, molecular dynamics simulations, and supervised machine learning (artificial neural-network) method are combined to extract PRDFs directly from experimental data. By applying this method to several systems of Pt and PdAu NPs, we demonstrate the finite size effects on the nearest neighbor distributions, bond dynamics, and alloying motifs in mono- and bimetallic particles and establish the generality of this approach.
Improving the selectivity for catalytic hydrogenation of alkynes is a key step in upgrading feedstocks for olefin polymerization. Herein, dilute Pd x Au1–x alloy nanoparticles embedded in raspberry colloid-templated silica (x = 0.02, 0.04, and 0.09) are demonstrated to be highly active and selective for the gas-phase hydrogenation of 1-hexyne, exhibiting higher selectivity than pure Pd at high conversion. The conversion of 1-hexyne remains high even for the very low amounts of Pd in Pd0.02Au0.98. These catalysts are highly resistant to sinteringaddressing a long-standing challenge in the use of Au-based catalysts. Clear evidence is presented that the addition of the second hydrogen to the half-hydrogenated intermediate is the rate-limiting step and that the stability of the half-hydrogenated intermediate of the alkyne is higher than the half-hydrogenated alkene, which explains the high selectivity even at high conversions. Moreover, of the three compositions investigated, optimum selectivity and activity are observed for the nanoparticles containing 4% Pd. The apparent activation energy for production of 1-hexene from 1-hexyne is measured to be 38 kJ mol–1 for the Pd0.04Au0.96 catalysts, which is ∼14 kJ mol–1 lower than for pure Pd. The hydrogenation is completely, but reversibly, suppressed by adding CO to the reactant mixture, indicating that the Pd centers are the active sites for reaction. The method of templating used in preparation of the catalysts is highly customizable and versatile. This study demonstrates that the composition of the nanoparticles as defined by the dilution ratio of Pd in Au and by the method used to make the supported catalyst is an important tunable parameter that can be used to optimize activity and selectivity of bimetallic systems.
Described is the surface coordination chemistry of cyclohexane, 1,3 and 1,4-cyclohexadiene and cyclohexene on the low Miller index planesand a stepped surface of nickel and on the platinum (111) (111) at 20-70°C. A similar behavior was observed for Pt(lll) at -35 to +135°C although a small degree of dehydrogenation was evident on this surface.
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