In this investigation the effect of Nopal mucilage on the electrochemical properties of concrete was evaluated. Three concentrations of this additive were designed with a Nopal-water ratio of 1:1, 1:2 and 1:3. Compressive tests were performed after 28 days of curing. Specimens were evaluated for 270 days through various electrochemical techniques such as: Open Circuit Potential (OCP), Electrochemical Noise (EN) and Linear Polarization Resistance (LPR). Results indicate a decrease in compressive resistance in samples with Nopal mucilage at 28 days. The onset of steel corrosion was delayed and the corrosion rate was lower for samples with Nopal mucilage. The conservation and storage of this additive before being used in concrete can be a challenge to analyze.
The corrosion behaviour of pure Al, Cu, 1018 carbon steel and 304 type stainless steel in Canola biodiesel during 528 hours has been evaluated by using electrochemical techniques. Techniques include open circuit potentials (OCP), electrochemical noise (EN) and electrochemical impedance spectroscopy (EIS) measurements at room temperature. These tests were complemented by scanning electronic microscopy, X-ray diffraction, infrared spectroscopy and gas mass chromatography analysis. Results have shown that carbon steel had the highest corrosion rate whereas Cu had the lowest corrosion rate. EN measurements indicated that 304 type stainless steel was moderately susceptible to pitting corrosion, whereas the rest of the metals were susceptible to either mixed or uniform type of corrosion. This was due to the degradation of the biodiesel as observed in an increase in its density, viscosity, acidity and water content at the end of the test.
A Ti6Al4V alloy was plasma-oxidized at 600 °C during 1, 2, 3, 5 and 8 h and corroded in an artificial saliva solution. Electrochemical evaluation was performed by using potentiodynamic polarization curves, linear polarization resistance (LPR), and electrochemical impedance spectroscopy (EIS) measurements during 100 h. Corroded specimens were characterized by using Raman spectroscopy and scanning electronic microscopy (SEM). All tests indicated that the highest corrosion resistance was obtained for specimen oxidized during 3 h since the noblest free corrosion potential, lowest passive and corrosion current density values, as well as the highest polarization resistance values were obtained under these circumstances. EIS measurements indicated that the highest impedance and phase angle values obtained for this specimen exhibited a high capacitive behavior typical of a very compact passive film.
The corrosion behavior of pure aluminum (Al) in 20 v/v% ethanol–gasoline blends has been studied using electrochemical techniques. Ethanol was obtained from different fruits including sugar cane, oranges, apples, or mangos, whereas other techniques included lineal polarization resistance, electrochemical noise, and electrochemical impedance spectroscopy for 90 days. Results have shown that corrosion rates for Al in all the blends were higher than that obtained in gasoline. In addition, the highest corrosion rate was obtained in the blend containing ethanol obtained from sugar cane. The corrosion process was under charge transfer control in all blends; however, for some exposure times, it was under the adsorption/desorption control of an intermediate compound. Al was susceptible to a localized, plotting type of corrosion in all blends, but they were bigger in size and in number in the blend containing ethanol obtained from sugar cane.
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