for compositions of the alloy from pure Bi to Bi saturated with Li3Bi(s) and for temperatures between 775 and 1100°K. The electrolyte consisted of 70 mole % LiCl and 30 mole % LiF. A secondary reference electrode which consisted of Bi saturated with LisBi(s) was used in most of the cells in place of the Li anode. Its potential was independently measured against the Li electrode. From the measurements, a least-squares derived equation relating the excess chemical potential (cal./mole) of Li in the alloy as a function of temperature and composition for the region studied was found to be µ = [9397 + 18.16 -0.0109 2] + [7103 -19.44 + 0.0068r2jZL;The standard free energy of formation of LiaBi(s) has been derived as a function of temperature.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.