The study of phase-transition dynamics in solids beyond a time-averaged kinetic description requires direct measurement of the changes in the atomic configuration along the physical pathways leading to the new phase. The timescale of interest is in the range 10(-14) to 10(-12) s. Until recently, only optical techniques were capable of providing adequate time resolution, albeit with indirect sensitivity to structural arrangement. Ultrafast laser-induced changes of long-range order have recently been directly established for some materials using time-resolved X-ray diffraction. However, the measurement of the atomic displacements within the unit cell, as well as their relationship with the stability limit of a structural phase, has to date remained obscure. Here we report time-resolved X-ray diffraction measurements of the coherent atomic displacement of the lattice atoms in photoexcited bismuth close to a phase transition. Excitation of large-amplitude coherent optical phonons gives rise to a periodic modulation of the X-ray diffraction efficiency. Stronger excitation corresponding to atomic displacements exceeding 10 per cent of the nearest-neighbour distance-near the Lindemann limit-leads to a subsequent loss of long-range order, which is most probably due to melting of the material.
Time-resolved x-ray diffraction with ultrashort ( approximately 300 fs), multi-keV x-ray pulses has been used to study the femtosecond laser-induced solid-to-liquid phase transition in a thin crystalline layer of germanium. Nonthermal melting is observed to take place within 300-500 fs. Following ultrafast melting we observe strong acoustic perturbations evolving on a picosecond time scale.
The onset of an electron parametric instability and 3/2 harmonic generation in variable-scale-length plasmas on solid surfaces using femtosecond pulses is observed. With the intensity approaching 10(18) W/cm(2), the instability threshold is already reached at plasma scale lengths of the order of the laser wavelength. A well-collimated harmonic emission with unusually broad spectrum is obtained.
Relatively small-scale laser-driven sources of short
wavelength radiation covering a range from the extreme
ultraviolet to the hard X-ray regime are now available.
Because the duration of the X-ray pulses is comparable
to, or shorter than the laser pulse width, it is possible
to carry out X-ray measurements with picosecond or femtosecond
time resolution.
Femtosecond / X-Ray / DiffractionFor a long time the capability to perform measurements with femtosecond time-resolution belonged exclusively to the domain of optics. However, in the last few years laser-driven X-ray sources have been developed which enable femtosecond time-resolution to be extended to the X-ray regime.
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