The detection of early failures in electromigration (EM) and the complicated statistical nature of this important reliability phenomenon have been difficult issues to treat in the past. A satisfactory experimental approach for the detection and the statistical analysis of early failures has not yet been established. This is mainly due to the rare occurrence of early failures and difficulties in testing of large sample populations. Furthermore, experimental data on the EM behavior as a function of varying number of failure links are scarce. In this study, a technique utilizing large interconnect arrays in conjunction with the well-known Wheatstone Bridge is presented. Three types of structures with a varying number of Ti/TiN/Al(Cu)/TiN-based interconnects were used, starting from a small unit of five lines in parallel. A serial arrangement of this unit enabled testing of interconnect arrays encompassing 480 possible failure links. In addition, a Wheatstone Bridge-type wiring using four large arrays in each device enabled simultaneous testing of 1920 interconnects. In conjunction with a statistical deconvolution to the single interconnect level, the results indicate that the electromigration failure mechanism studied here follows perfect lognormal behavior down to the four sigma level. The statistical deconvolution procedure is described in detail. Over a temperature range from 155 to 200 °C, a total of more than 75 000 interconnects were tested. None of the samples have shown an indication of early, or alternate, failure mechanisms. The activation energy of the EM mechanism studied here, namely the Cu incubation time, was determined to be Q=1.08±0.05 eV. We surmise that interface diffusion of Cu along the Al(Cu) sidewalls and along the top and bottom refractory layers, coupled with grain boundary diffusion within the interconnects, constitutes the Cu incubation mechanism.
The intent of this research is to understand the role of interface chemistry on the effective work function and device characteristics of metal gate electrodes on hafnium dioxide (HfO2) gate dielectrics in metal oxide semiconductor field effect transistors. Since multiple factors, including crystal structure, preferred orientation, chemical composition, interface bonding, and reactions or interdiffusions, impact the effective work function, solid-solution carbonitrides of tantalum (TaCxN1−x) have been studied in an attempt to isolate the role of interface chemistry on the effective work function. Tantalum carbonitride films have been carefully deposited with similar Ta∕(C+N) ratios to understand how the substitution of N for C on the octahedral interstice in a face-centered-cubic tantalum lattice impacts device performance. Results indicate that the effective work function and device threshold voltage are reduced when the less electronegative carbon atom is substituted for the more electronegative nitrogen atom. This result is in qualitative agreement with the known relationship between metal electronegativity and effective work function and demonstrates the important role that sublattice elements in binary metal compounds have on the effective work function of the gate electrode.
IntroductionA high performance 0.20pm logic technology has been developed with six levels of planarized copper interconnects. 0.15pm transistors (Lg,,,=0.15+0.04pm) are optimized for 1.8V operation to provide high performance with low power-delay products and excellent reliability. Copper has been integrated into the back-end to provide low resistance interconnects. Critical layer pitches for the technology are summarized in Table 1 and enable fabrication of 7.6pm2 6T SRAM cells.Isolation and Transistors CMP planarized shallow trenches with good electrical isolation down to n+/p+ spacings of 0.5pm were fabricated (Fig. 1). Dual gate 0.15pm transistors with 35A physical gate oxides (accumulation t,,=39A measured at Vg=+l .SV) were formed using super steep retrograde channels, shallow extensions and halos, relatively deep source/drain regions and 1 OOnm nitride spacers. CoSi, was selectively formed on the polysilicon gates and source/drain regions with a nominal sheet resistance of 9Wsq. Rapid thermal processing was utilized as much as possible throughout the flow to minimize transient enhanced dopant diffusion.Fig. 2 shows a typical SEM cross-section of a NMOS transistor with a gate length of 0.15pm. Well delineated shallow S/D extensions and the deeper S/D junctions are clearly observed. The saturation drive currents for nominal gate length NMOS and PMOS devices are shown in Fig. 3 . The nominal drive currents are 630pNpm for NMOS and 230pA/ym for PMOS at 1.8V. The off-state leakage currents of these devices are well below the worst case leakage specification of 2nA/pm. The drain induced barrier lowering (DIBL) measured on NMOS and PMOS devices is plotted as a function of Leff in Fig. 4. Good short channel characteristics are maintained down to effective channel lengths of O.1ym. The Vt roll-off for N and P devices in the linear and saturation regions are shown in Fig. 5. The Vt's are 0.44V and -0.46V for Nch and Pch respectively, at a gate length of 0.15pm and the associated subthreshold slopes are less than 90mv/dec. The use of nitrided gate oxides was investigated due to their superior hot carrier reliability. Fig. 6 compares the degradation under hot carrier stress of nitrided oxides to thermal oxides and highlights the improved reliability of NO-annealed oxides. Peak Gms comparable to those from thermal oxides were obtained (Fig. 7). A further advantage afforded by nitrided gate dielectrics is its superior boron blocking properties, Increasing the poly silicon doping in the P+ gate to reduce poly depletion resulted in only a 88mV Vt shift in nitrided oxides (Fig. 8) compared to a 300mV Vt shift in thermal oxides. A significant reduction in the inversion to, is achieved with the higher gate doping, resulting in improved device characteristics. NMOS transistor design focused on minimizing defect enhanced dopant re-distribution such as TED. To this end, the effect of different source/drain implant energies on NMOS transistor performance is shown in Fig. 9. The lower energy implant results in a significantl...
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