Interfacial properties of cellulose nanocrystals (CNC) and surfactants were studied in high ionic strength (I) brines and correlated to the stability of dodecane/brine Pickering emulsions. Bis-(2-hydroxyethyl) cocoalkylamine (CAA), dodecyltrimethylammonium bromide (DTAB), and octyl-β-d-glucopyranoside (OGP) were adsorbed onto CNC in American Petroleum Institute (API) brine (I = 1.9 M) and synthetic seawater (SSW), with I = 0.65 M. Raman spectroscopy indicated that hydroxyl groups on the CNC surface interact with all three surfactants in high ionic strength media. Ionic interactions still play a role at the very large ionic strengths studied herein. Despite all surfactants adsorbing onto CNC, only the surface tension of CAA solutions in both brines was increased by the addition of 0.5 wt % CNC. The effect was much more prominent in API than in SSW. Contact angle measurements indicated that CAA increased the wettability of CNC by both brines in dodecane; DTAB, on the other hand, decreased wettability. Emulsion stability studies revealed that ionic strength, wettability, adsorption energy, and oil content strongly affect emulsion stability, more so than surfactant adsorption. In API, CNC aggregates alone stabilized the emulsions better compared to samples with additional emulsifiers; the same was true in SSW for oil contents below 50% v/v. For oil contents above 50% v/v in SSW, CAA was either detrimental or failed to improve emulsion stability. On the other hand, DTAB increased the stability of dodecane in SSW emulsions. Emulsions stable for over 21 months were prepared with oil contents of 75% v/v. The adsorption of CAA onto CNC limits the migration of both CNC and CAA to the dodecane/brine interface, while DTAB adsorption has the opposite effect.

Ternary and Pseudo-ternary phase behavior of the system water/hexadecane/dioctyl sodium sulfosuccinate (DSS)/sorbitan 1aurate has been determined.The mi croemuls i on regi on of thi s alcohol-free system has potential for use as a pharmaceutical topical vehicle.A 1/1 weight ratio of sorbitan laurate:DSS (60:40)/hexadecane can solubil ize up to 55% water, while sobitan 1aurate: DSS ratios larger than 70/30 show dramat i cally decreased water solubilization at equivalent hexadecane concentrations.