The preparation of
blue-emitting black phosphorus quantum dots
(BPQDs) is based on the liquid-phase exfoliation of bulk BP. We report
the synthesis of soluble BPQDs showing a strong visible blue-light
emission. Highly fluorescent (photoluminescence quantum yield of ≈5%
with the maximum emission (λmax) at ≈437 nm)
and dispersible BPQDs in various organic solvents are first prepared
by simple ultrasonication of BP crystals in chloroform in the ambient
atmosphere. Furthermore, simple mussel-inspired surface functionalization
of BPQDs with catechol-grafted poly(ethylene glycol) in basic buffer
afforded water-soluble blue-emitting BPQDs showing long-term fluorescence
stability, very low cytotoxicity, and excellent fluorescence live
cell imaging capability.
Carbon aerogel is a porous carbon material possessing high porosity and high specific surface area. Nitrogen doping reduced the specific surface area and micropores, but it furnished basic sites to improve the CO 2 selectivity. In this work, N-doped carbon aerogels were prepared with different ratios of resorcinol/melamine by using the sol-gel method. The morphological properties were characterized by scanning electron microscopy (SEM). Nitrogen content was studied by X-ray photoelectron spectroscopy (XPS) and the specific surface area and micropore volume were analyzed by N 2 adsorption-desorption isotherms at 77 K. The CO 2 adsorption capacity was investigated by CO 2 adsorption-desorption isotherms at 298 K and 1 bar. Melamine containing N-doped CAs showed a high nitrogen content (5.54 wt.%). The prepared N-doped CAs exhibited a high CO 2 capture capacity of 118.77 mg/g (at resorcinol/melamine = 1:0.3). Therefore, we confirmed that the CO 2 adsorption capacity was strongly affected by the nitrogen moieties.
In recent decades, there has been an increasing interest in the use of carbon fiber reinforced plastic (CFRP) in aerospace, renewable energy and other industries, due to its low weight and relatively good mechanical properties compared with traditional metals. However, due to the high cost of petroleum-based precursors and their associated processing costs, CF remains a specialty product and as such has been limited to use in high-end aerospace, sporting goods, automotive, and specialist industrial applications. The high cost of CF is a problem in various applications and the use of CFRP has been impeded by the high cost of CF in various applications. This paper presents an overview of research related to the fabrication of low cost CF using polyethylene (PE) control technology, and identifies areas requiring additional research and development. It critically reviews the results of cross-linked PE control technology studies, and the development of promising control technologies, including acid, peroxide, radiation and silane cross-linking methods.
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