We explore the feasibility of probing atom-wall interaction with atomic clocks based on atoms trapped in engineered optical lattices. Optical lattice is normal to the wall. By monitoring the wall-induced clock shift at individual wells of the lattice, one would measure the dependence of the atom-wall interaction on the atom-wall separation. We find that the induced clock shifts are large and observable at already experimentally demonstrated levels of accuracy. We show that this scheme may uniquely probe the long-range atom-wall interaction in all three qualitatively distinct regimes of the interaction: van der Waals (image-charge interaction), Casimir-Polder (QED vacuum fluctuations), and Lifshitz (thermal-bath fluctuations) regimes.

Direct laser writing of conductive paths in synthetic diamond is of interest for implementation in radiation detection and clinical dosimetry.Unraveling the microscopic processes involved in laser irradiation of diamond below and close to the graphitization threshold under the same conditions of the experimental procedure used to produce three-dimensional (3D) devices is necessary to tune the laser parameters to optimal results. To this purpose a Transient Currents Technique (TCT) has been used to measure laser-induced current signals in monocrystalline diamond detector in a wide range of laser intensities and at different bias voltages. The current transients vs. time and the overall charge collected have been compared with theoretical simulations of the carrier dynamics along the duration and after the conclusion of the 30 fs laser pulse. The generated charge has been derived from the collected charge by evaluation of the lifetime of the carriers. The plasma volume has also been evaluated by measuring the modified region.The theoretical simulation has been implemented in the framework of empirical pseudopotential method extended to include time-dependent couplings of valence electrons to the radiation field. The simulation, in the low intensity regime, I ∼ 1 TW/cm 2 , predicts substantial deviation from the traditional multiphoton ionization, due to non-perturbative effects involving electrons from degenerate valence bands. For strong field with intensity of about 50 TW/cm 2 , non-adiabatic effects of electron-hole pair excitation become prominent with high carrier densities eventually causing the optical breakdown of diamond.The comparison of theoretical prediction with experimental data of laser generated charge vs. laser energy density yields a good quantitative agreement over six orders of magnitude. At the highest intensities the change of slope in the trend is explained taking into account the dependence of the optical parameters and the carrier mobility on plasma density.

We calculate the density shift and broadening of selected dipole transition lines of pionic helium in gaseous helium at low temperatures up to T = 12 K and pressure up to a few bar. In the approximation of binary collisions the shift and broadening depend linearly on the density; we evaluate the slope of this linear dependence for a few spectral lines of known experimental interest, and also investigate its temperature dependence. We find a blue shift of the resonance frequencies of the