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Thermal modification is the most important commercial modification procedure. Thermally modified (TM) wood has improved durability, but its performance does not meet expectations predominately under moist conditions. To reduce water uptake of TM wood, Norway spruce specimens were treated with suspensions of a natural wax by dipping impregnation (DipI) or by vacuum-pressure impregnation (VPI). Wax-treated specimens were subsequently TM at 185, 200, 215, and 230°C. Control specimens were heated up to 100°C only. Contact angle (CA), short-term and long-term water uptake, bending strength, and performance against wood decay fungi of the resulting material were determined. The results show that a combination of wax treatment and thermal modification have a synergistic effect that considerably improves hydrophobicity, reduces liquid water uptake, slows down water vapor uptake, and improves the resistance against fungal decay of the treated material.

To cite this version:Boštjan Lesar, Miha Humar. Use of wax emulsions for improvement of wood durability and sorption properties. European Journal of Wood and Wood Products, Springer Verlag, 2010, pp.231-238 Waxes are used for treatment of wood surfaces for several decades predominately as surface treatments because they weakly penetrate into the wood. In order to overcome this issue, water emulsions were applied in the present experiment. Five water emulsions of various concentrations were used, namely montan wax, polyethylene, ethylene copolymer and oxidized polyethylene wax.Performance of wax treated beech (Fagus sylvatica) and Norway spruce (Picea abies) against white rot, brown rot and blue stain fungi was tested. In parallel, sorption properties of wax treated wood were determined. The treated specimens were more resistant to wood decay fungi.Polyethylene and oxidized polyethylene wax were found to be particularly efficient. Although this treatment does not improve resistance to blue stain fungi, it reduces the sorption of water. Die Verwendung von Wachsemulsionen zur Verbesserung der

Wood is one of the most important construction materials, and its use in building applications has increased in recent decades. In order to enable even more extensive and reliable use of wood, we need to understand the factors affecting wood’s service life. A new concept for characterizing the durability of wood-based materials and for predicting the service life of wood has recently been proposed, based on material-inherent protective properties, moisture performance, and the climate- and design-induced exposure dose of wooden structures. This approach was validated on the decking of a model house in Ljubljana that was constructed in October 2013. The decay and moisture content of decking elements were regularly monitored. In addition, the resistance dose DRd, as the product of the critical dose Dcrit, and two factors taking into account the wetting ability of wood (kwa) and its inherent durability (kinh), were determined in the laboratory. DRd correlated well with the decay rates of the decking of the model house. Furthermore, the positive effect of thermal modification and water-repellent treatments on the outdoor performance of the examined materials was evident, as well as the synergistic effects between moisture performance and inherent durability.

The importance of the aesthetic performance of wood is increasing and the colour is one of the most important parameters of aesthetics, hence the colour stability of twelve different wood-based materials was evaluated by several in-service and laboratory tests. The wood used for wooden façades and decking belongs to a group of severely exposed surfaces. Discolouration of wood in such applications is a long-known phenomenon, which is a result of different biotic and abiotic causes. The ongoing in-service trial started in October 2013, whilst a laboratory test mimicking seasonal exposure was performed in parallel. Samples were exposed to blue stain fungi (Aureobasidium pullulans and Dothichiza pithyophila) in a laboratory test according to the EN 152 procedure. Afterwards, the same samples were artificially weathered and re-exposed to the same blue stain fungi for the second time. The purpose of this experiment was to investigate the synergistic effect of weathering and staining. The broader aim of the study was to determine the correlation factors between artificial and natural weathering and to compare laboratory and field test data of fungal disfigurement of various bio-based materials. During the four years of exposure, the most prominent colour changes were determined on decking. Respective changes on the façade elements were significantly less prominent, being the lest evident on the south and east façade. The results showed that there are positive correlations between natural weathering and the combination of artificial weathering and blue staining. Hence, the artificial weathering of wood-based materials in the laboratory should consist of two steps, blue staining and artificial weathering, in order to simulate colour changes.

Chemical protection is one of the possible treatment processes that influence the sorption characteristics of wood. In the present research we have investigated the influence of biocides (boric acid, borax) and their concentrations on the sorption characteristic of impregnated wood. For comparison, two other chemicals were included in the research as well (NaCl and glucose). The equilibrium moisture content during the adsorption and desorption process at five levels of relative humidity (u 1 ¼ 20%, u 2 ¼ 33%, u 3 ¼ 65%, u 4 ¼ 88%, and u 5 ¼ 98%) was monitored. The results showed that impregnation does not influence the wood moisture content of specimens conditioned at low relative air humidity. In the upper hygroscopic region, moisture content is significantly influenced by the concentration and properties of impregnation chemicals. The Guggenheim-Andersen-deBoer (GAB) and Dent models of sorption isotherms was fitted to experimental data to explain the sorption mechanisms in detail.

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