Mobile charged defects, accumulated in the domain-wall region to screen polarization charges, have been proposed as the origin of the electrical conductivity at domain walls in ferroelectric materials. Despite theoretical and experimental efforts, this scenario has not been directly confirmed, leaving a gap in the understanding of the intriguing electrical properties of domain walls. Here, we provide atomic-scale chemical and structural analyses showing the accumulation of charged defects at domain walls in BiFeO. The defects were identified as Fe cations and bismuth vacancies, revealing p-type hopping conduction at domain walls caused by the presence of electron holes associated with Fe. In agreement with the p-type behaviour, we further show that the local domain-wall conductivity can be tailored by controlling the atmosphere during high-temperature annealing. This work has possible implications for engineering local conductivity in ferroelectrics and for devices based on domain walls.
Using a homogeneous precipitation method in an ultrasound field, we synthesized nanosized, platelike hydroxyapatite (HAp). The internal structure of these platelike formations consists of specifically oriented and laterally connected nanorods. The synthesized HAp nanorods have a length of about 500 nm and a diameter of about 100 nm. A closer inspection of the microstructure of a single nanorod revealed a highly regular and defect-free lattice with unique crystallographic plane orientations. The obtained structure was related to the influence of the ultrasound on the growth mechanism. The samples were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).
We report on the properties of a new air-stable nanowire material with the chemical formula
Mo6S3I6. The distinguishing features of the material are rapid one-step synthesis, easy isolation and
controllable dispersion into small-diameter wire bundles. Elemental analysis, x-ray
diffraction, thermogravimetry, differential thermal analysis, Raman scattering and electron
microscopy were used to characterize the material.
We have synthesized large quantities of sodium-titanate-based nanotubes and nanoribbons with high yields under hydrothermal conditions from anatase powder in an aqueous NaOH solution. The reaction temperatures were from 95 to 195 degrees C, in steps of 20 degrees C. We observed that the morphology of the nanomaterials, which is reflected in their specific surface areas, depends strongly on the reaction temperature. For the materials synthesized in the range 95-135 degrees C and above 155 degrees C only a single morphology type was observed for the nanostructures, i.e., nanotubes and nanoribbons, respectively. In contrast, when the reaction was carried out at 155 degreesC, both nanotubes and nanoribbons were found in the product. SEM, TEM, and XRD techniques were used to determine the materials' morphological and structural properties, and the thermal stability of the materials was investigated with TGA and DSC. The largest weight loss, of approximately 25%, was observed in a temperature range from 25 up to 600 degrees C for the product obtained at 95 degrees C, probably due to the presence of unrolled titanate sheets.
The local crystal and domain structures of K0.5Bi0.5TiO3 ceramics were investigated by transmission electron microscopy (TEM) and selected‐area electron diffraction (SAED). The individual grains showed a lamellar domain structure, and on the basis of spot splitting along the characteristic crystallographic directions, 90°a–a‐ and 90°a–c‐type domains were identified. Furthermore, lamellar features within the 90° domains were observed, which we presumed were 180° domains; however, in the case of P4mm structures they cannot be distinguished by SAED. The 90° domain boundaries were (011) and (101) twin planes, typical for tetragonal perovskites. The domains could be designated as rotation twins, where the symmetry element describing the relationship between two twin domains is a twofold twin axis [011]/[101] and the symmetry operation is a 180° rotation. In order to determine the dynamics and the temperature of the phase transformation from the tetragonal to the cubic structures, high‐temperature XRD and in situ heating TEM analyses were performed. The results showed a gradual phase transformation in the temperature range from ∼280° to ∼450°C, where some grains lost their polar domains at a lower temperature than others. These findings confirmed the existence of a binary stability field in which the cubic and tetragonal structures coexist.
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