We report on the properties of a new air-stable nanowire material with the chemical formula
Mo6S3I6. The distinguishing features of the material are rapid one-step synthesis, easy isolation and
controllable dispersion into small-diameter wire bundles. Elemental analysis, x-ray
diffraction, thermogravimetry, differential thermal analysis, Raman scattering and electron
microscopy were used to characterize the material.
Actinomycetes have been proven to be an excellent source of secondary metabolites for more than half a century. Exhibiting various bioactivities, they provide valuable approved drugs in clinical use. Most microorganisms are still untapped in terms of their capacity to produce secondary metabolites, since only a small fraction can be cultured in the laboratory. Thus, improving cultivation techniques to extend the range of secondary metabolite producers accessible under laboratory conditions is an important first step in prospecting underexplored sources for the isolation of novel antibiotics. Currently uncultured actinobacteria can be made available by bioprospecting extreme or simply habitats other than soil. Furthermore, bioinformatic analysis of genomes reveals most producers to harbour many more biosynthetic gene clusters than compounds identified from any single strain, which translates into a silent biosynthetic potential of the microbial world for the production of yet unknown natural products. This review covers discovery strategies and innovative methods recently employed to access the untapped reservoir of natural products. The focus is the order of actinomycetes although most approaches are similarly applicable to other microbes. Advanced cultivation methods, genomics- and metagenomics-based approaches, as well as modern metabolomics-inspired methods are highlighted to emphasise the interplay of different disciplines to improve access to novel natural products.
Liquid crystal elastomers (LCE) are currently of great interest due to conjoining of mesogenic ordering and rubber elasticity, exhibited in their large spontaneous thermally stimulated changes in shape. It has been shown that nanoparticles (nanotubes, photo-isomerisable dyes, magnetic nanoparticles.) can be incorporated into these LCE networks to create a more sensitive network to external stimuli (i.e. strain or stress, optical, electrical, electro-thermal, magnetic.). Here, we briefly summarise the current state of LCE-nanoparticle systems and explain in detail one system utilising carbon nanoparticles integrated at surfaces that may be used for electro-thermal heating of LCE systems.
We report on the synthesis of quasi‐1D W5O14 crystals using NiI2 as a growth promoter. Photoelectron spectroscopy revealed the metallic conductivity of the W5O14 nanowires, which was also confirmed by direct‐transport measurements on a double‐stranded nanowire. Scanning electron microscopy and transmission electron‐diffraction data are correlated with details of crystal growth revealing the possible mechanism of the formation of this rarely synthesized phase, which was reported as a homogeneous phase only in 1978 by McColm et al., and in the meantime has been declared as a compound that is rare.
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