In this paper, a triazine‐based flame retardant (TAT) was synthesized from cyanuric chloride and aniline. Its chemical structure was characterized by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance, and elemental analysis. Two kinds of novel intumescent flame‐retardant epoxy systems were obtained with the incorporation of TAT and 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) or hexa‐phenoxy‐cyclotriphosphazene (HPCP). The flame retardancy of the obtained epoxy samples was evaluated using limited oxygen index, vertical burning (UL94), and cone calorimeter tests. The results indicated that there was a synergistic effect between TAT and DOPO or HPCP. The flame‐retardant mechanism was investigated by thermogravimetric analysis (TGA), thermogravimetric analysis/infrared spectrometry (TGA‐FTIR) coupled with the morphology and chemical analysis of the char residues. During combustion, DOPO or HPCP decomposed to release phosphorus‐containing free radicals with quenching effect. The morphology study showed that the introduction of DOPO or HPCP promoted the carbonization of epoxy matrix and the formation of a phosphorus‐containing viscous char layer, while the pyrolysis gases derived from the decomposition of TAT caused the char layer to expand. The main reason of the promotion of flame retardancy of epoxy samples was that the simultaneous addition of TAT and DOPO or HPCP led to the formation of a compact and intumescent char layer that restricted the transfer of heat and combustible volatiles and simultaneously protected the underlying matrix.
Totally enclosed water-cooled permanent magnet machines have been widely applied in electric vehicles due to their advantages of high torque density, high power factor and strong overloading capacity. However, this type of machine often suffers extremely high ambient temperature in very limited space, which may lead to serious faults during operation, such as demagnetization. In order to study the thermal performance in depth, after investigation on the air convection within end-space, this paper presents a thermal model, which takes into account the influence of the air temperature within the end-space on the temperature distribution by convection. Combining electromagnetic finiteelement analysis with thermal resistance network, the thermal model is established, which is based on the law of heat flux balance in two continuous iterative calculations. Furthermore, computational fluid dynamic technology and experiments are implemented to further validate the proposed thermal model.
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