Various site specific energy transfer (ET) process such as Tb3+@Ca2 → Eu3+@Ca1, Tb3+@Ca1 → Eu3+@Ca2 and Tb3+@Ca1 → Eu3+@Ca1 were explored in Eu3+ and Tb3+ co-doped Ca10(PO4)6F2 phosphor, which are responsible for tunable colour characteristics.
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