Deciphering depositional age from deposits that accumulate in deep-water slope settings can enhance understanding of shelf-margin evolutionary timing, as well as controlling mechanisms in ancient systems worldwide. Basin analysis has long employed biostratigraphy and/or tephrochronology to temporally constrain ancient environments. However, due to poor preservation of index fossils and volcanic ash beds in many deepwater systems, deducing the timing of slope evolution has proven challenging. Here, we present >6600 new U-Pb zircon ages with stratigraphic information from an ~100-kmlong by ~2.5-km-thick outcrop belt to elucidate evolutionary timing for a Campanian-Maastrichtian slope succession in the Magallanes Basin, Chile. Results show that the succession consists of four stratigraphic intervals, which characterize four evolutionary phases of the slope system. Overall, the succession records 9.9 ± 1.4 m.y. (80.5 ± 0.3 Ma to 70.6 ± 1.5 Ma) of graded clinoform development punctuated by out-of-grade periods distinguished by enhanced coarse-grained sediment bypass downslope. Synthesis of our results with geochronologic, structural, and stratigraphic data from the basin suggests that slope evolution was largely controlled by an overall decline in basin subsidence from 82 to 74 Ma. In addition to providing insight into slope evolution, our results show that the reliability of zircon-derived depositional duration estimates for ancient sedimentary systems is controlled by: (1) the proportion of syndepositionally formed zircon in a strati

Scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) have been used to examine the structure of ordered adlayers of Ca on TiO 2 (110)-1×1 formed by metal vapor deposition. A comparison is made with structures formed by segregation of Ca from the bulk, with similar structures being found for the two preparation methods below a monolayer coverage. At low coverages, rows of width ∼0.6-0.9 nm develop in the [11 h0] and [001] azimuths. At coverages equivalent to a single calcium layer, a c(6×2) overlayer is formed. At coverages above a single layer, a disordered structure develops and a LEED pattern with ( -0.1 2 1 0 ) symmetry is observed.

Scanning tunneling microscopy and core level photoelectron spectroscopy measurements have been used to investigate the morphology of ZnO(0001 macro)-O, and its reactivity with carbon monoxide and carbon dioxide, as a function of surface preparation. Real space images of the surface indicate that increasing the substrate anneal temperature during preparation significantly reduces the surface step density. Surface defect concentration is also monitored by employing formic acid as a chemical probe, which is shown to adsorb dissociatively (HCOOH --> [HCOO](-) + H(+)) only on zinc cations at step edges. Carbon 1s X-ray photoelectron spectra show that carbon monoxide and carbon dioxide both react to form surface carbonate species. Spectra, recorded both as a function of surface preparation and following coadsorption, demonstrate that the carbonate formed from either reactant molecule is located at oxygen vacancies at step edges, evidencing the significant role that defects can play in the surface chemistry of ZnO(0001 macro)-O.

The Late Jurassic to Early Cretaceous fill of the Western Interior foreland basin is characterized using geochronological data in order to assess the stratigraphic expression of wedge-top geomorphology, as controlled by sediment cover and denudation. In northern Montana, USA, and Alberta, Canada, wedge-top deposits are poorly preserved; however, their former presence may be inferred from the detrital record in the foreland basin. We present new U/Pb detrital zircon data from nine samples collected near Great Falls, Montana, augmented with field data. The stratigraphy at Great Falls is characterized by Late Jurassic marine and nonmarine deposits, which are truncated by a basinwide sub-Cretaceous unconformity. Aptian and lower Albian strata overlying the unconformity are dominated by nonmarine deposits, which transition up-section into a predominantly marine succession related to a major transgression of the Boreal Seaway in the Albian.Detrital zircon grains from Great Falls strata yield age spectra that can be subdivided into three groups using multidimensional scaling. Group 1 is characterized by diverse zircon populations, which are interpreted to record recycling of pre-Cordilleran sedimentary strata transported via foreland basin-axial river systems with headwaters in the southwestern United States. Group 2 is characterized by the dominance of Mesozoic detrital zircon grains, which are interpreted to record sediment dispersal by fluvial systems with headwaters in the Cordillera. Group 3 is intermediate between groups 1 and 2, based on its proportion of Mesozoic zircon grains. This group records a diversification of the provenance from one dominated by Cordilleran igneous rocks to include recycled sedimentary strata.New data are integrated with three other data sets from Montana and Alberta such that stratal thicknesses (a proxy for accommodation development) and provenance evolution can be compared across the basin. The detrital record in each area, which transitions from diverse provenance to predominantly Cordilleran through the entire stratigraphic section, can be linked to the burial of the pre-foreland strata in the wedge-top depozone. This record elucidates a period of evolution of the western margin of North America to a more Andean-type system with primary input to the basin from an active magmatic arc.

No abstract