A green, simple, and cost effective electrochemical method to synthesize pure graphene oxide (GO) and graphene nanosheets (GNs) using pencil in ionic liquid medium is reported. The morphology and microstructure of prepared GNs and GO are examined using scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), X‐ray diffraction (XRD), and Raman spectroscopy; the experiments confirm the formation of high quality graphene. The synthesized GO is used for the real‐time and label‐free surface plasmon resonance (SPR) sensing of the biological warfare agent Salmonella typhi.

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Ionic liquids (ILs) are salt that exist in the liquid phase at and around 298 K and are comprised of a bulky, asymmetric organic cation and the anion usually inorganic ion but some ILs also with organic anion. ILs have attracted much attention as a replacement for traditional organic solvents as they possess many attractive properties. Among these properties, intrinsic ion conductivity, low volatility, high chemical and thermal stability, low combustibility, and wide electrochemical windows are few. Due to negligible or nonzero volatility of these solvents, they are considered “greener” for the environment as they do not evaporate like volatile organic compounds (VOCs). ILs have been widely used in electrodeposition, electrosynthesis, electrocatalysis, electrochemical capacitor, lubricants, plasticizers, solvent, lithium batteries, solvents to manufacture nanomaterials, extraction, gas absorption agents, and so forth. Besides a brief discussion of the introduction, history, and properties of ILs the major purpose of this review paper is to provide an overview on the advantages of ILs for the synthesis of conducting polymer and nanoparticle when compared to conventional media and also to focus on the electrochemical sensors and biosensors based on IL/composite modified macrodisk electrodes. Subsequently, recent developments and major strategies for enhancing sensing performance are discussed.

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Chemical warfare agents (CWA) pose inevitable threat, both to soldiers and civilians. Risk on contact with these deadly agents can be avoided by neutralisation of their toxic effects. A suitable media with essential physico-chemical properties is required for this purpose. Considerable efforts have been made to develop several decontamination media suitable for neutralisation of highly toxic CWAs. This paper reviews history and details of recent technological advancements in the development of versatile, broad spectrum decontamination formulations against CWAs, as also nanosized metal oxides as CWA decontaminants.

in Wiley InterScience (www.interscience.wiley.com).Decontamination reactions of sulfur mustard and sarin were studied on the surface of titania nanotubes and the data were compared with that of bulk titania. Before the reaction studies, titania nanotube samples were made by using hydrothermal method and were characterized by scanning electron microscopy, N 2 BET, X-ray diffractometry, and thermogravimetry. Soon after that, titania nanotube samples were exposed to sulfur mustard and sarin separately at room temperature (308C) and the reactions were monitored by gas chromatography, whereas the reaction products were characterized by GC-MS. The data explore the role of hydrolysis reactions and surface reactions for the decontamination of both sulfur mustard and sarin.

Climate change and global warming have been two massive concerns for the scientific community during the last few decades. Anthropogenic emissions of greenhouse gases (GHGs) have greatly amplified the level of greenhouse gases in the Earth's atmosphere which results in the gradual heating of the atmosphere. The precise measurement and reliable quantification of GHGs emission in the environment are of the utmost priority for the study of climate change. The detection of GHGs such as carbon dioxide, methane, nitrous oxide and ozone is the first and foremost step in finding the solution to manage and reduce the concentration of these gases in the Earth's atmosphere. The nanostructured metal oxide semiconductor (NMOS) based technologies for sensing GHGs emission have been found most reliable and accurate. Owing to their fascinating structural and morphological properties metal oxide semiconductors become an important class of materials for GHGs emission sensing technology. In this review article, the current concentration of GHGs in the Earth's environment, dominant sources of anthropogenic emissions of these gases and consequently their possible impacts on human life have been described briefly. Further, the different available technologies for GHG sensors along with their principle of operation have been largely discussed. The advantages and disadvantages of each sensor technology have also been highlighted. In particular, this article presents a comprehensive study on the development of various NMOS-based GHGs sensors and their performance analysis in order to establish a strong detection technology for the anthropogenic GHGs. In the last, the scope for improved sensitivity, selectivity and response time for these sensors, their future trends and outlook for researchers are suggested in the conclusion of this article.