We present electronic and transport properties of a zigzag nanoribbon made of α − T3 lattice. Our particular focus is on the effects of the continuous evolution of the edge modes ( from flat to dispersive) on the thermoelectric transport properties. Unlike the case of graphene nanoribbon, the zigzag nanoribbon of α − T3 lattice can host a pair of dispersive (chiral) edge modes at the two valleys for specific width of the ribbon. Moreover, gap opening can also occur at the two valleys depending on the width. The slope of the chiral edge modes and the energy gap strongly depend on the relative strength of two kinds of hoping parameters present in the system. We compute corresponding transport coefficients such as conductance, thermopower, thermal conductance and the thermoelectric figure of merits by using the tight-binding Green function formalism, in order to explore the roles of the dispersive edge modes. It is found that the thermopower and thermoelectric figure of merits can be enhanced significantly by suitably controlling the edge modes. The figure of merits can be enhanced by thirty times under suitable parameter regime in comparison to the case of graphene. Finally, we reveal that the presence of line defect, close to the edge, can cause a significant impact on the edge modes as well as on electrical conductance and thermopower.
This study explores the effects of electro-magneto-hydrodynamics, Hall currents, and convective and slip boundary conditions on the peristaltic propulsion of nanofluids (considered as couple stress nanofluids) through porous symmetric microchannels. The phenomena of energy and mass transfer are considered under thermal radiation and heat source/sink. The governing equations are modeled and non-dimensionalized under appropriate dimensionless quantities. The resulting system is solved numerically with MATHEMATICA (with an in-built function, namely the Runge-Kutta scheme). Graphical results are presented for various fluid flow quantities, such as the velocity, the nanoparticle temperature, the nanoparticle concentration, the skin friction, the nanoparticle heat transfer coefficient, the nanoparticle concentration coefficient, and the trapping phenomena. The results indicate that the nanoparticle heat transfer coefficient is enhanced for the larger values of thermophoresis parameters. Furthermore, an intriguing phenomenon is observed in trapping: the trapped bolus is expanded with an increase in the Hartmann number. However, the bolus size decreases with the increasing values of both the Darcy number and the electroosmotic parameter.
Several parts of the Moringa oleifera plant have revealed incredible potential for water quality improvement. However, the purification potential of a combined leaf and seed extract of Moringa oleifera plants remains unexplored. To the best of our knowledge, this research would be the first to work towards exploiting the combined potential of a leaf and seed extract of the Moringa oleifera plant in the process of water purification. In this study, we investigated the combined effectiveness of the leaf and seed extract in the purification of groundwater. The jar test method was used to analyze the effectiveness of Moringa plant extract (in combination) on different quality parameters of groundwater. Treatment with the combined plant extract (seed and leaf) resulted in significant improvement of various physicochemical (hardness, pH, turbidity, Total Dissolved Solid (TDS), and metallic impurities) and biological parameters (E.coli count) over individual seed and leaf extracts in groundwater samples. Experimental findings have strongly shown the enhanced purification efficacy of the hexane extract of combined plant materials in comparison to the individual extracts, thereby providing us with a potent natural coagulant that could combat the side effects of chemical coagulants.
A novel copper-zinc-manganese trimetal oxide nanocomposite was synthesized by the simple co-precipitation method for sensing glucose and methylene blue degradation. The absorption maximum was found by ultraviolet–visible spectroscopy (UV-Vis) analysis, and the bandgap was 4.32 eV. The formation of a bond between metal and oxygen was confirmed by Fourier Transform Infrared Spectroscopy (FT-IR) analysis. The average crystallite size was calculated as 17.31 nm by X-ray powder diffraction (XRD) analysis. The morphology was observed as spherical by scanning electron microscope (SEM) and high-resolution transmission electron microscopy (HR-TEM) analysis. The elemental composition was determined by Energy Dispersive X-ray Analysis (EDAX) analysis. The oxidation state of the metals present in the nanocomposites was confirmed by the X-ray photoelectron spectroscopy (XPS) analysis. The hydrodynamic diameter and zeta potential of the nanocomposite were 218 nm and −46.8 eV, respectively. The thermal stability of the nanocomposite was analyzed by thermogravimetry-differential scanning calorimetry (TG-DSC) analysis. The synthesized nanocomposite was evaluated for the electrochemical glucose sensor. The nanocomposite shows 87.47% of degradation ability against methylene blue dye at a 50 µM concentration. The trimetal oxide nanocomposite shows potent activity against Escherichia coli. In addition to that, the prepared nanocomposite shows strong antioxidant application where scavenging activity was observed to be 76.58 ± 0.30, 76.89 ± 0.44, 81.41 ± 30, 82.58 ± 0.32, and 84.36 ± 0.09 % at 31, 62, 125, 250, and 500 µg/mL, respectively. The results confirm the antioxidant potency of nanoparticles (NPs) was concentration dependent.
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